The scarcity of Groundwater on Earth increases the necessity to make full use of the ubiquitous atmospheric water (H2O). Photocatalytic conversion of the H2O from the air to hydrogen (H-2) under visiblelight irradiation by metal-free conjugated polymer photocatalysts (CMPs) would be an interesting and challenging route for fully utilizing H2O resources and converting to sustainable and green energy. However, there is no such strategy reported up to now, to the best of our knowledge. Here, for the first time, we used various CMPs for H-2 production using captured moisture by ionic liquids (ILs) under visible-light irradiation. The presence of ILs in the H2O-absobed H2O/ILs mixtures could enhance photocatalytic H-2 evolution rate when compared to the pure H2O. Particularly, the accelerated effect of [BMIM][BF4] was the highest (29-fold), with the highest H-2 production rate of 96.5 gmol g(-1) h(-1) among all the IL-related systems investigated. We attributed the high efficiency of H2 photo-evolution from atmospheric H2O to the activation of H2O by ILs and the highly dispersion of photocatalysts in H2O/ILs system. This work might open a new field to convert sustainable and ubiquitous atmospheric H2O resources to clean H2 fuels. (C) 2019 Elsevier Ltd. All rights reserved.