화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.83, 100-110, March, 2020
DOI10.1016/j.jiec.2019.11.018  Export Citation
Mesoporous copper zinc bimetallic imidazolate MOF as nanofiller to improve gas separation performance of PEBA-based membranes
Rokhsare Kardani1, Morteza Asghari1, 2, †, Naghmeh Faal Hamedani3, and Morteza Afsari1
  • 1Separation Processes Research Group (SPRG), Department of Engineering, University of Kashan, Kashan, Iran
  • 2Energy Research Institute, University of Kashan, Kashan, Iran
  • 3Department of Chemistry, Faculty of Valiasr, Tehran Branch, Technical and Vocational University (TVU), Tehran, Iran
E-mail:
CO2-philic copper zinc bimetallic imidazolate framework (CuZnIF) particles were synthesized and introduced into poly (ether block amide) (PEBA) matrix in the range of 0.1.10 wt.% to fabricate mixed matrix membranes (MMMs) with enhanced performance for CO2 separation. The effects of nanoparticle loading and feed pressure on the separation performance of the MMMs were investigated. The CuZnIF particles were characterized by FTIR, FESEM, XRD, BJH and BET tests. The nanocomposite membrane containing 0.5 wt.% of CuZnIF showed the best performance; CO2 permeability, CO2/N2 and CO2/CH4 selectivity of MMMs were improved about 47, 61 and 30%, respectively.
Keywords:Mixed matrix membrane;Poly(ether block amide);MOF;Copper-zinc bimetallic imidazolate;framework;Carbon dioxide separation
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