A copper complex based catalytic conversion and isolation of carbonate from CO2 for the carbon sequestration process

Dharmalingam Sivanesan; Bongkuk Seo; Choong-Sun Lim; Hyeon-Gook Kim

Journal of Industrial and Engineering Chemistry, Vol.83, 271-278, March, 2020

DOI10.1016/j.jiec.2019.11.037 Export Citation

A copper complex based catalytic conversion and isolation of carbonate from CO2 for the carbon sequestration process

Dharmalingam Sivanesan, Bongkuk Seo, Choong-Sun Lim, and Hyeon-Gook Kim^†

Advanced Industrial Chemistry Research Center, Advanced Convergent Chemistry Division, Korea Research Institute of Chemical Technology (KRICT), 45 Jonggaro, Ulsan, 44412 South Korea

E-mail:

The conversion of CO2 into value-added chemicals of industrial significance is of great interest due to global warming-related concerns and the depletion of natural resources. This paper describes a mononuclear copper complex with an N3S coordination environment that can catalyze the conversion of CO2 into the carbonate anion with an ambient O2. Electrochemical studies indicate that the N3S-ligated Cu(II) complex can be reduced to Cu(I), which can subsequently generate the carbonate anion from CO2 and ambient O2. In presence of LiClO4 when the N3S-ligated complex Cu(II) is reduced to Cu(I), the complex easily releases the carbonate anion which easily precipitates as Li2CO3 in CH3CN. These studies suggest that the N3S-ligated Cu(II)/(I) complexes can be used to convert CO2 to carbonate and isolate the generated carbonate.

Keywords:CO2 fixation;Copper complex;Electrocatalyst;Carbonate generation;Carbonate isolation

[References]

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[1] (a) Branden CI, Schneider G, Reduction in Biological, Model Systems, Oxford University Press, New York, 1994; (b) Tappe NA, Reich RM, D’Elia V, Kuhn FE, Dalton Trans., 47, 13281 (2018).

[2] (a) Dabral S, Schaub T, Adv. Synth. Catal., 361, 223 (2019); (b) Yua B, Zoua B, Hua CW, Journal of CO₂ Utilization, 26, 314 (2018); (c) Yu B, He LN, Chem. Sus. Chem, 8, 52 (2015); (d) Cao Y, He X, Wang N, Li H, He LN, Chin. J. Chem.. 36. 644 (2018).

[3] (a) Song CS, Catal. Today., 115, 2 (2006); (b) Takeda H, Cometto C, Ishitani O, Robert M, ACS Catal., 7, 70 (2017).

[4] (a) Artz J, Muller TE, Thenert K, Kleinekorte J, Meys R, Sternberg A, Bardow A, Leitner W, Chem. Rev, 118, 434 (2018); (b) Yadav N, Seidi F, Crespy D, D’Elia V, Chem. Sus. Chem, 12, 724 (2019).

[5] (a) Moret S, Dyson PJ, Laurenczy G, Nat. Commun, 5, 4017 (2014); (b) Ogo S, Kabe R, Hayashi H, Harada R, Fukuzumi S, DaltonTrans., 4657 (2006); (c) Lu SM, Wang ZJ, Li J, Xiao JL, Li C, Green Chem., 18, 4553 (2016).

[6] (a) Bond GM, McPherson BJ, Abel A, Lichtner P, Grigg R, Liu N, Stringer J, Proceedings of the Second National Conference on Carbon Sequestration, Alexandria, VA, 2003 May 5; (b) Sivanesan D, Bhatti UH, Youn MH, Park KT, Kim HJ, Grace AN, Choi SH, Jeong SK, ACS Sustainable Chem. Eng., 7, 11955 (2019).

[7] Blencoe JG, Anovitz LM, Palmer DA, Beard JS, Proceedings of the Second National Conference on Carbon Sequestration, DOE NETL, Alexandria, VA, 2003 May 5-8, 2003.

[8] Goldberg P, Chen ZY, O’Connor W, Walters R, Ziock H, Proceedings of the First National Conference on Carbon Sequestration, DOE NETL, Washington, DC, 2001 May 14-17, 2001.

[9] LACKNER KS, WENDY CH, BUTT DP, JOYCE EL, SHARP DH, Energy, 20(11), 1153 (1995)

[10] Wright J, Colling A, Properties and Behavior, 2nd edition, Pergamon-Elsevier, Oxford, 1995.

[11] (a) Lippert CA, Liu K, Sarma M, Parkin SR, Remias JE, Brandewie CM, Odom SA, Liu K, Catal. Sci. Technol, 4, 3620 (2014); (b) Sivanesan D, Choi Y, Lee J, Youn MH, Park KT, Grace AN, Kim HJ, Jeong SK, Chem. Sus. Chem., 8, 3977 (2015); (c) Bhatti UH, Shah AK, Kim JN, You JK, Choi SH, Lim DH, Nam S, Park YH, Baek IH, ACS Sustainable Chem. Eng., 5, 5862 (2017); (d) Choi YC, Sivanesan D, Lee J, Youn MH, Park KT, Kim HJ, Grace AN, Kim IH, Jeong SK, J. Ind. Eng. Chem., 34, 76 (2016).

[12] (a) Sivanesan D, Kim YE, Youn MH, Park KT, Kim HJ, Grace AN, Jeong SK, RSC Adv, 6, 64575 (2016); (b) Sivanesan D, Park KT, Lee JY, Park IG, Jeong SK, J. Ind. Eng. Chem., 68, 335 (2018); (c) Sivanesan D, Youn MH, Murnandari A, Kang JM, Park KT, Kim HJ, Jeong SK, J. Ind. Eng. Chem., 52, 287 (2017).

[13] (a) Zhao Z, Kong X, Yuan Q, Xie H, Yang D, Zhao J, Fan H, Jiang L, Phys. Chem. Chem. Phys, 20, 19314 (2018); (b) Vaid TP, Kelley SP, Rogers RD, Dalton Trans., 46, 8920 (2017).

[14] Garcia-Espana E, Gavina P, Latorre J, Soriano C, Verdejo BA, J. Am. Chem. Soc., 126(16), 5082 (2004)

[15] Comba P, Gahan LR, Hanson GR, Maeder M, Westphal M, Dalton Trans., 43, 3144 (2014)

[16] Massoud SS, Louka FR, Al-Hasan MA, Vicente R, Mautner FA, New. J. Chem, 39, 5944 (2015)

[17] Pavlishchuk VV, Addison AW, Inorg. Chim. Acta., 298, 97 (2000)

[18] Sheldrick GM, Program Library for Structure Solution, Molecular Graphics: Version 6.2, Madison, WI, Bruker AXS, 2000.

[19] Sheldrick GM, SADABS: Area-Detector Absorption Correction, University of Gottingen, Gottingen, Germany, 2001

[20] Spek AL, PLATON, A Multipurpose Crystallographic Tool, Utrecht University, Utrecht, The Netherlands, 2000.

[21] Salvatore RN, Smith RA, Nischwitza AK, Gavin T, Tetrahedron Lett., 46, 8931 (2005)

[22] (a) Lucas HR, Li L, Sarjeant AAN, Vance MA, Solomon EI, Karlin KD, J. Am. Chem. Soc., 131, 3230 (2009); (b) Maiti D, Sarjeant AAN, Karlin KD, J. Am. Chem. Soc., 129, 6720 (2007); (c) Dharmalingam S, Youn MH, Park KT, Kim HJ, Graceb AN, Jeong SK, Acta Cryst. C,73, 1024 (2017).

[23] Angamuthu R, Byers P, Lutz M, Spek AL, Bouwman E, Science, 327(5963), 313 (2010)

[24] Zhang CX, Kaderli S, Costas M, Kim E, Neuhold YM, Karlin KD, Zuberbuhler AD, Inorg. Chem., 42(6), 1807 (2003)

[25] Lee DH, Hatcher LYQ, Vance MA, Sarangi R, Milligan AE, Sarjeant AAN, Incarvito CD, Rheingold AL, Hodgson KO, Hedman B, Solomon EI, Karlin KD, Inorg. Chem., 46(15), 6056 (2007)