화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.37, No.5, 911-920, May, 2020
DOI10.1007/s11814-020-0485-6  Export Citation
A monophosphonic group-functionalized ion-imprinted polymer for a removal of Fe3+ from highly concentrated basic chromium sulfate solution
Guang-jin Zhu1, 2, Hai-yan Tang1, 2, †, Peng-hui Qing1, 2, Hong-ling Zhang1, 2, Xi-chuan Cheng3, Zai-hua Cai3, Hong-bin Xu1, 2, and Yi Zhang1, 2
  • 1CAS Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China
  • 2National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China
  • 3Hubei Zhenhua Chemical Co., LTD, Huangshi 435001, Hubei Province, China
E-mail:
An ion-imprinted polymer (IIP) with monophosphonic groups was prepared by thermal copolymerization. Bis(2-methacryloxyethyl) phosphate (BMAOP) was used as functional monomer to react with Fe3+ in dimethyl sulfoxide (DMSO). Ethylene glycol dimethacrylate (EGDMA) was used as cross-linker during polymerization process. A suitable molar ratio of BMAOP to Fe3+ was investigated by UV/Vis/NIR Spectrometer and ICP-OES. The obtained results showed that the monophosphonic groups could be selectively combined with Fe3+ in solutions containing other coexisting ions, and the selectivity could be further enhanced by ion-imprinted process. The prepared IIP was used for removing trace Fe3+ from high concentration basic chromium sulfate solutions. After adsorption process, the concentration of Fe3+ could be reduced from 4.486mg L?1 to 0.171mg L?1, which was much lower than the concentration in the solution treated by non-imprinted polymer (NIP). Moreover, the IIP exhibited excellent recyclability after six adsorption-desorption cycles.
Keywords:Ion-imprinted Polymer;Basic Chromium Sulfate;Selective Adsorption;Fe3+ Removal;Thermal Copolymerization
  1. Ma Y, Wang X, Wang M, Jiang C, Xiang X, Zhang X, Hydrometallurgy, 153, 38 (2015)
  2. Hu GP, Chen DS, Wang LN, Liu JC, Zhao HX, Liu YH, Qi T, Zhang CQ, Yu P, Sep. Purif. Technol., 125, 59 (2014)
  3. Yang X, Zhang YM, Bao SX, Shen C, Sep. Purif. Technol., 164, 49 (2016)
  4. Mei H, Li G, Wang K, Li X, Inorg. Chem. Ind., 34, 34 (2002)
  5. Weng H, Chem. World, 35, 50 (1994)
  6. Liu A, Jia L, Chin. Leather, 36, 26 (2007)
  7. Guo C, Yi S, Plat. Finish., 30, 28 (2008)
  8. Chen X, Chin. Leather, 38, 1 (2009)
  9. Chen X, Inorg. Chem. Ind., 46, 13 (2014)
  10. Li X, Chen N, Zhang G, Qin L, Yin T, Chrom. Ind., 1, 48 (2010)
  11. Wang G, Zhao Y, Yang B, Song Y, Hydrometallurgy, 176, 69 (2018)
  12. Zhang Y, Zhou X, Liu Z, Li B, Liu Q, Li X, Rsc Adv., 6, 6695 (2016)
  13. Lee MS, Nicol MJ, Hydrometallurgy, 86, 6 (2007)
  14. Nishide H, Deguchi J, Tsuchida E, Chem. Lett., 5, 169 (1976)
  15. Birlik E, Ersoz A, Acikkalp E, Denizli A, Say R, J. Hazard. Mater., 140(1-2), 110 (2007)
  16. Branger C, Meouche W, Margaillan A, React. Funct. Polym., 73(6), 859 (2013)
  17. Saatcilar O, Satiroglu N, Say R, Bektas S, Denizli A, J. Appl. Polym. Sci., 101(5), 3520 (2006)
  18. Fu J, Chen L, Li J, Zhang Z, J. Mater. Chem. A, 3, 13598 (2015)
  19. Liang H, Chen Q, Shen X, J. Nucl. Radiochem., 38, 129 (2016)
  20. Randhawa M, Gartner I, Becker C, Student J, Chai M, Mueller A, J. Appl. Polym. Sci., 106(5), 3321 (2007)
  21. Dam AH, Kim DJ, J. Appl. Polym. Sci., 108(1), 14 (2008)
  22. Ashyuce S, Bereli N, Uzun L, Onur MA, Say R, Denizli A, Sep. Purif. Technol., 73(2), 243 (2010)
  23. Cimen D, Gokturk I, YIlmaz F, Artif. Cells Nanomed. Biotechnol., 44, 1158 (2016)
  24. Ergun B, Baydemir G, Andac M, Yavuz H, Denizli A, J. Appl. Polym. Sci., 125(1), 254 (2012)
  25. Ozkara S, Say R, Andac C, Denizli A, Ind. Eng. Chem. Res., 47(20), 7849 (2008)
  26. Yavuz H, Say R, Denizli A, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 25, 521 (2005)
  27. Fan HT, Sun T, Korean J. Chem. Eng., 29(6), 798 (2012)
  28. Khajeh M, Kaykhaii M, Hashemi H, Mirmoghaddam M, Polym. Sci. Ser. B, 51, 344 (2009)
  29. Ozkara S, Andac M, Karakoc V, Say R, Denizli A, J. Appl. Polym. Sci., 120(3), 1829 (2011)
  30. Singh DK, Mishra S, J. Sci. Ind. Res., 69, 767 (2010)
  31. Roushani M, Beygi TM, Saedi Z, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 153, 637 (2016)
  32. Chang X, Jiang N, Zheng H, He Q, Hu Z, Zhai Y, Cui Y, Talanta, 71, 38 (2007)
  33. Zhu GJ, Tang HY, Zhang HI, Pei Ll, Zhou P, Shi YL, Cai ZH, Xu HB, Zhang Y, Hydrometallurgy, 186, 105 (2019)
  34. McKevitt B, Dreisinger D, Hydrometallurgy, 98, 122 (2009)
  35. McKevitt B, Dreisinger D, Hydrometallurgy, 98, 116 (2009)
  36. He H, Gan Q, Feng C, J. Appl. Polym. Sci., 134, 45165 (2017)
  37. Komiyama M, Takeuchi T, Mukawa T, Asanuma H, from fundamentals to applications, Sci. Press, Beijing (2003).
  38. Liang HL, Chen QD, Ma JY, Huang YY, Shen XH, Rsc Adv., 7, 35394 (2017)
  39. Formanek J, Jandova J, Capek, Hydrometallurgy, 138, 100 (2013)
  40. El-Nadi YA, E-Hefny NE, Chem. Eng. Process., 49(2), 159 (2010)
  41. Li P, Zheng SL, Qing PH, Chen YG, Tian L, Zheng XD, Zhang Y, Green Chem., 16, 4214 (2014)
  42. Parijaee M, Noaparast M, Saberyan K, Shafaie-Tonkaboni SZ, Korean J. Chem. Eng., 31(12), 2237 (2014)
  43. Weber W, Morris J, J. Sanit. Eng. Div. Am. Soc. Civ. Eng., 89, 31 (1963)
  44. Hameed BH, Tan IAW, Ahmad AL, Chem. Eng. J., 144(2), 235 (2008)
  45. Juang RS, Wu FC, Tseng RL, J. Colloid Interface Sci., 227(2), 437 (2000)
  46. Zhou JB, Wang L, Zhang Z, Yu JG, J. Colloid Interface Sci., 394, 509 (2013)
  47. Chen X, Pan J, Yan Y, Acta Phys.-Chim. Sin., 32, 2794 (2016)
  48. Li Z, Kou W, Wu S, Wu L, Anal. Methods, 9, 3221 (2017)