In recent years, catalytic hydrolysis of sodium borohydride is considered to be a promising approach for hydrogen generation towards fuel cell devices, and highly efficient and noble-metal-free catalysts have attracted increasing attention. In our present work, Co3O4 nanocubes are synthesized by solvothermal method, and then vapor-phase phosphorization treatment is carried out for the preparation of novel Co-O-P composite nanocatalysts composed of multiple active centers including Co, CoO, and Co2P. For catalyst characterization, field-emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), energy dispersive spectrometry (EDS), X-ray diffraction (XRD) and X-ray photoelectric spectroscopy (XPS) are conducted. Optimal conditions for catalyst preparation and application were investigated in detail. At room temperature (25 degrees C), maximum hydrogen generation rate (HGR) is measured to be 4.85 L min(-1) g(-1) using a 4 wt% NaBH4-8 wt% NaOH solution, which is much higher than that of conventional catalysts with single component reported in literature. It is found that HGR remarkably increases with the increasing of reaction temperature, and apparent activation energy for catalytic hydrolysis of NaBH4 is calculated to be 63 kJ mol(-1). After reusing for five times, the Co-O-P composite nanocatalysts still retains 78% of the initial activity. (C) 2020 Published by Elsevier Ltd on behalf of Hydrogen Energy Publications LLC.