Hydrogen is a major component of low heating value (LHV) fuels like syngas, coke oven gas, and blast furnace gas. These fuels can potentially replace methane in the industrial process under MILD combustion conditions. NOx formation mechanism in MILD combustion regime is different from conventional air combustion due to uniform temperature distribution and low oxygen concentration. Hence, it is important to investigate the effect of hydrogen addition inmethane (CH4) on different NOx formation mechanism and pathways under MILD combustion conditions. A well-stirred reactor (WSR) model with atmospheric pressure and long residence time was employed to simulate the ideal MILD combustion conditions with Chemkin Pro software and GRI Mech 2.11. H-2 and CH4 blends ranging from 0% H-2 (100% CH4) to 60% H-2 (B60 = 40%CH4/60%H-2) were selected as fuels to emulate MILD combustion of LHV fuels. The oxygen mass fraction was kept from 3% to 9%, and the fuel blends were altered. The results showed that hydrogen addition enhanced NNH route while decreasing prompt route and N2O intermediate route whereas thermal NOx route was insignificant for lower O-2 mass fraction of 3% and 6%. It was observed that H-2 addition reduced NO-reburning which led to more NOx emission. Moreover, the sensitivity analysis was conducted to analyze the pathway of NOx formation and to quantitively separate the relative contribution of the individual route on the total NOx formation, which was beneficial to control the NOx emission of LHV fuels during MILD combustion. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.