화학공학소재연구정보센터
International Journal of Hydrogen Energy, Vol.45, No.4, 3307-3315, 2020
Hydrogen release from carbon steel in chloride solution under anodic polarization
The hydrogen permeation current increase was noticed for carbon steel in 0.5 mol/L NaCl solution under strong anodic potentials, which is contrary to the common understanding. Hydrogen permeation under cathodic potentials has been widely studied because of possible hydrogen embrittlement failures of high strength steels in seawater, but investigations of anodic polarization on hydrogen permeation are fairly rare, as the hydrogen evolution reaction shall be retarded. To corroborate the observed phenomenon, experiments were conducted using both as-received and vacuum-annealed sheet specimens. It was verified that the observed phenomena originated from the released hydrogen in traps by metal dissolution under anodic polarization. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.