We perform dynamics simulations of donor-bridge-acceptor triads following photoexcitation and correlate nuclear motions with the charge-transfer event using the short-time Fourier transform technique. Broadly, the porphyrin bridges undergo higher energy vibrations, whereas the fullerene acceptors undergo low energy modes. Aryl side groups exhibit torsional motions relative to the porphyrin. Aryl linkers between the bridge and acceptor are restricted from such motions and therefore express ring distortion modes. Finally, we find an amide linker mode that is directionally sensitive to electron motion. This work supports the notion of vibrationally coupled ultrafast charge transfer found in both experimental and theoretical studies and lays a foundational method for identifying key vibrational modes for parametrizing future theoretical models.