This paper investigated the chemical bonding features and conductivity characteristics of atmospheric pressure plasma (APP) conducting polymerized polypyrrole (pPPy) by iodine (I-2) doping method in coupling and remote conditions, respectively. The I-2 doped APP pPPy film surfaces were analyzed by field-emission scanning electron microscopy (FE-SEM). Fourier transform infrared spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), and X-ray diffraction (XRD) analyses were used to determine the crystallinity and chemical bond of I-2 doped APP pPPy film for both coupling and remote conditions, respectively. In terms of crystallinity and bonding structure, I-2 doped APP pPPy film, which was obtained by coupling condition, had own advantages, such as existence of abundant multiple bond (C equivalent to C/C equivalent to N) with pi-electron, improved crystallinity, and lower initial resistance compared to that of remote condition. Whereas, the dense and thick I-2 doped APP pPPy film obtained by remote condition was less hydrated and shown lower resistivity change-rate under ambient air compared to that of coupling condition. Therefore, different resistivity and humidity characteristics of I-2 doped APP pPPy films depending on growth condition such as remote and coupling conditions contribute to increasing the possibility of using the I-2 doped APP pPPy film as flexible electrode-materials.