화학공학소재연구정보센터
Journal of the Electrochemical Society, Vol.143, No.3, 905-907, 1996
Electrochromic Behavior of a Lambda-MnO2 Electrode Accompanying Li+-Insertion in an Aqueous-Phase
Electrochromism of spinel-type manganese oxide accompanying an Li+-insertion in an aqueous phase was examined ted by visual light spectrometry. An absorbance spectrum for lithiated manganese oxide gave lower absorbance in the wavelength range <700 nm than did an Li+-extracted one. The greatest difference was observed at similar to 450 nm and is explained by the difference between the spectra for Mn3+ and Mn4+. A reversible change in absorbance at 450 nm occurred with the Li+-insertion/extraction reaction. Cyclic voltammetry indicated that the absorbance change couples with the electrochemical response of the manganese oxide to Li+ ions.