Spin current historically referred to the flow of electrons carrying spin information, in particular since the discovery of giant magnetoresistance in the 1980s. Recently, it has been found that spin current can also be mediated by spin-triplet supercurrent, superconducting quasiparticles, spinons, magnons, spin superfluidity and so on. Here, we review key progress concerning the developing research direction utilizing spin current as a probe of quantum materials. We focus on spin-triplet superconductivity and spin dynamics in the ferromagnet/superconductor heterostructures, quantum spin liquids, magnetic phase transitions, magnon-polarons, magnon-polaritons, magnon Bose-Einstein condensates and spin superfluidity. The unique characteristics of spin current as a probe will be fruitful for future investigation of spin-dependent properties and the identification of new quantum materials. Progress in utilizing spin current as a probe of quantum materials,-including topological insulators, superconductors, spin liquids, magnonic systems and spin superfluidity,-is reviewed.