Rapid charge extraction and transfer is a crucial prerequisite to achieve high-performance perovskite solar cells, however, the notorious non-radiative recombination pathways limit the further efficiency enhancement owing to the energy barriers between charge transporting layers and perovskite layers. Aiming to realize the accelerated charge extraction and reduced charge loss, in the current work, formamidinium lead halide (FAPbX(3), X = Cl, Br, or I) perovskite nanocrystals are successfully fabricated using high-melting-point ligands to modify the perovskite/carbon interface in all-inorganic CsPbBr3 perovskite solar cells, which are regarded as promising photovoltaic device because of their superior stability under rigorous conditions comparing to organic-inorganic hybrid perovskite solar cells. By optimizing the composition of FAPbX(3) perovskite nanocrystals, an elevated power conversion efficiency up to 8.55% is achieved owing to the enhanced charge transfer kinetics and reduced charge recombination loss, demonstrating the Importance of interface control in high-performance photovoltaic platforms.