Ion-association dispersive liquid.liquid microextraction of trace amount of gold in water samples and ore using Aliquat 336 prior to inductivity coupled plasma atomic emission spectrometry determination

Naeemeh Zari; Jalal Hassan; Kourosh Tabar-Heydar; Seyyed Hamid Ahmadi

Journal of Industrial and Engineering Chemistry, Vol.86, 47-52, June, 2020

DOI10.1016/j.jiec.2017.01.038 Export Citation

Ion-association dispersive liquid.liquid microextraction of trace amount of gold in water samples and ore using Aliquat 336 prior to inductivity coupled plasma atomic emission spectrometry determination

Naeemeh Zari, Jalal Hassan^{1, †}, Kourosh Tabar-Heydar, and Seyyed Hamid Ahmadi

Environmental Chemistry and Green Technology Department, Chemistry and Chemical Engineering Research Center of Iran, P.O. Box 14335-186, Tehran, Iran
¹Division of Toxicology, Department of Basic Sciences, Faculty of Veterinary Medicine, University of Tehran, Tehran, Iran

E-mail:

An extraction method employing dispersive liquid.liquid microextraction (DLLME) and ICP-OES has been developed for rapid separation, pre-concentration and determination of ultra-trace amount of Au (III). The extraction of the analyte was performed in the presence of a quaternary ammonium cation, NMethyl- N, N, N-trioctylammonium chloride, (Aliquat 336) as an extractant based on ion-association extraction system.1-octanol and acetonitrile were used as extraction and disperser solvents, respectively. The variables affecting the extraction conditions were optimized. Calibration curve in the range of 0.3. 100 ng mL-1, the detection limit of 0.09 ng mL-1, enrichment factor of 150 and extraction recovery of 74% were obtained. The precision (R.S.D. %) of the method was 6% for 5 replicates and recoveries of 10 ng mL-1 Au(III). The combined DLLME method with ICP-OES can readily determine Au(III) at trace (μg L-1) level using only 10 mL of sample solution (tap, lake, and mining water) and ore sample without interference by the matrices. This methodology is simple, fast, and low cost which can be used in routine analytical laboratories.

Keywords:Gold;Dispersive liquid-liquid microextraction;Aliquat 336;Inductively coupled plasma atomic;emission spectrometry

[References]

Aitio A, Kiilunen M, Santonen T, Nordberg M, 4th ed., Handbook on the Toxicology of Metals, vol. 2 ISBN: 978-0-444-59453-2, Chapter 38, p. 817 (2014).
Kagaya S, Takata D, Yoshimori T, Kanbara T, Tohda K, Talanta, 80, 1364 (2010)
Lee JD, Concise Inorganic Chemistry, 5th ed., ELBS with Chapman and Hall, London, 1996.
Rancis SM, NiKolic-Mandic SD, Mandic LM, Anal. Chim. Acta, 547, 144 (2005)
Shamsipour M, Ramezani M, Talanta, 75, 294 (2008)
Gomez MM, McLeod CW, J. Anal. At. Spectrom., 8, 461 (1993)
Ye R, Khoo SB, Analyst, 124, 353 (1999)
Hu Q, Chen X, Yang X, Huang Z, Chen J, Yang G, Anal. Sci., 22, 627 (2006)
de Souza Pereira C, Mantovano JL, Turci CC, De MM, Fereira E, Microchem J., 115, 121 (2014)
Ye J, Liu S, Tina M, Li W, Hu B, Zhou W, Jia O, Talanta, 118, 231 (2014)
Yilmaz E, Soylak M, RSC Adv., 4, 47396 (2014)
Elci L, Sahan D, Basaran A, Environ. Monit. Assess., 132, 331 (2007)
Zhang L, Zhenhua L, Zheng H, Xijun C, Spectrochim. Acta A, 79, 1234 (2011)
Sabermahani F, Taher MA, Bahrami H, Arabian J. Chem. https://doi.org/10.1016/ (in press, Corrected Proof, Available online 9 May 2012).
Afzali D, Daliri Z, Taher MA, Arabian J. Chem., 7, 770 (2014)
Kazemi E, DadFarnia S, Haji Sabani AM, Talanta, 141, 273 (2015)
Manzoori J, Abdolmohammad-Zade LH, Amjadi M, Microchim. Acta, 159, 71 (2007)
Tavakoli L, Yamini Y, Ebrahimzadeh H, Nezhadali A, Shariati S, Nourmohammadian F, J. Hazard. Mater., 152(2), 737 (2008)
Messerschmidt J, Bohlen AV, Alt FR, Klocken Kamper R, Analyst, 125, 397 (2000)
El-Shahawi MS, Bshammakh AS, Bahaffi SO, Talanta, 72, 1494 (2007)
Vasilyeva A, Yudelevich IG, Gindin LM, Lanbina TV, Shulaman RS, Kotlaversky IL, Andrievsky VN, Talanta, 22, 745 (1975)
Ohava T, Matsumoto S, Yamamoto H, Shibata J, Baba Y, Solvent Extr. Res. Dev. -Jpn., 3, 213 (1995)
Kolekar SS, Anuse MA, Gold Bull., 34(2), 50 (2001)
Pena- Periera F, Lavilla I, Bendico C, Spectrochim. Acta B, 64, 1 (2009)
Das NR, Bhatacharyya SN, Talanta, 23, 535 (1976)
Rezaee M, Yamini Y, Faraji M, J. Chromatogr. A, 1217, 2342 (2010)
Anthemidis AN, Ionnp KLG, Talanta, 80, 413 (2009)
Leong MI, Fuh MR, Huang SD, J. Chromatogr. A, 1335, 2 (2014)
Mohammadi SZ, Afzali D, Taher MA, Baghelania YM, Microchim. Acta, 168, 123 (2010)
Mohammadi SZ, Afzali D, Taher MA, Baghelania YM, Talanta, 80, 875 (2009)
Mohammadi SZ, Afzali D, Baghelania YM, Anal. Chim. Acta, 653, 173 (2009)
DeLa Calle, Pena-pereira F, Cabaleiro N, Lvilla I, Bandicho C, Talanta, 84, 109 (2011)
Kocuroua L, Balogh IS, Skrilikova J, Posta J, Andruch V, Talanta, 82, 1958 (2010)
Yana H, Wanga H, J. Chromatogr. A, 1295, 1 (2013)
Boorn AW, Browner RF, Anal. Chem., 54, 1402 (1982)
Pak AAH, Gold Eploration, University Press, Tehran, 2002 ISSBN 964-03-4180-0.
Yamini Y, Moradi M, Tahmaseb E, Anal. Chim. Acta, 728, 26 (2012)
Tajic S, Taher MA, Microchim. Acta, 173, 249 (2011)
Elci L, Soylak M, Buyuksekarci EB, Anal. Sci., 19, 1621 (2003)

[1] Aitio A, Kiilunen M, Santonen T, Nordberg M, 4th ed., Handbook on the Toxicology of Metals, vol. 2 ISBN: 978-0-444-59453-2, Chapter 38, p. 817 (2014).

[2] Kagaya S, Takata D, Yoshimori T, Kanbara T, Tohda K, Talanta, 80, 1364 (2010)

[3] Lee JD, Concise Inorganic Chemistry, 5th ed., ELBS with Chapman and Hall, London, 1996.

[4] Rancis SM, NiKolic-Mandic SD, Mandic LM, Anal. Chim. Acta, 547, 144 (2005)

[5] Shamsipour M, Ramezani M, Talanta, 75, 294 (2008)

[6] Gomez MM, McLeod CW, J. Anal. At. Spectrom., 8, 461 (1993)

[7] Ye R, Khoo SB, Analyst, 124, 353 (1999)

[8] Hu Q, Chen X, Yang X, Huang Z, Chen J, Yang G, Anal. Sci., 22, 627 (2006)

[9] de Souza Pereira C, Mantovano JL, Turci CC, De MM, Fereira E, Microchem J., 115, 121 (2014)

[10] Ye J, Liu S, Tina M, Li W, Hu B, Zhou W, Jia O, Talanta, 118, 231 (2014)

[11] Yilmaz E, Soylak M, RSC Adv., 4, 47396 (2014)

[12] Elci L, Sahan D, Basaran A, Environ. Monit. Assess., 132, 331 (2007)

[13] Zhang L, Zhenhua L, Zheng H, Xijun C, Spectrochim. Acta A, 79, 1234 (2011)

[14] Sabermahani F, Taher MA, Bahrami H, Arabian J. Chem. https://doi.org/10.1016/ (in press, Corrected Proof, Available online 9 May 2012).

[15] Afzali D, Daliri Z, Taher MA, Arabian J. Chem., 7, 770 (2014)

[16] Kazemi E, DadFarnia S, Haji Sabani AM, Talanta, 141, 273 (2015)

[17] Manzoori J, Abdolmohammad-Zade LH, Amjadi M, Microchim. Acta, 159, 71 (2007)

[18] Tavakoli L, Yamini Y, Ebrahimzadeh H, Nezhadali A, Shariati S, Nourmohammadian F, J. Hazard. Mater., 152(2), 737 (2008)

[19] Messerschmidt J, Bohlen AV, Alt FR, Klocken Kamper R, Analyst, 125, 397 (2000)

[20] El-Shahawi MS, Bshammakh AS, Bahaffi SO, Talanta, 72, 1494 (2007)

[21] Vasilyeva A, Yudelevich IG, Gindin LM, Lanbina TV, Shulaman RS, Kotlaversky IL, Andrievsky VN, Talanta, 22, 745 (1975)

[22] Ohava T, Matsumoto S, Yamamoto H, Shibata J, Baba Y, Solvent Extr. Res. Dev. -Jpn., 3, 213 (1995)

[23] Kolekar SS, Anuse MA, Gold Bull., 34(2), 50 (2001)

[24] Pena- Periera F, Lavilla I, Bendico C, Spectrochim. Acta B, 64, 1 (2009)

[25] Das NR, Bhatacharyya SN, Talanta, 23, 535 (1976)

[26] Rezaee M, Yamini Y, Faraji M, J. Chromatogr. A, 1217, 2342 (2010)

[27] Anthemidis AN, Ionnp KLG, Talanta, 80, 413 (2009)

[28] Leong MI, Fuh MR, Huang SD, J. Chromatogr. A, 1335, 2 (2014)

[29] Mohammadi SZ, Afzali D, Taher MA, Baghelania YM, Microchim. Acta, 168, 123 (2010)

[30] Mohammadi SZ, Afzali D, Taher MA, Baghelania YM, Talanta, 80, 875 (2009)

[31] Mohammadi SZ, Afzali D, Baghelania YM, Anal. Chim. Acta, 653, 173 (2009)

[32] DeLa Calle, Pena-pereira F, Cabaleiro N, Lvilla I, Bandicho C, Talanta, 84, 109 (2011)

[33] Kocuroua L, Balogh IS, Skrilikova J, Posta J, Andruch V, Talanta, 82, 1958 (2010)

[34] Yana H, Wanga H, J. Chromatogr. A, 1295, 1 (2013)

[35] Boorn AW, Browner RF, Anal. Chem., 54, 1402 (1982)

[36] Pak AAH, Gold Eploration, University Press, Tehran, 2002 ISSBN 964-03-4180-0.

[37] Yamini Y, Moradi M, Tahmaseb E, Anal. Chim. Acta, 728, 26 (2012)

[38] Tajic S, Taher MA, Microchim. Acta, 173, 249 (2011)

[39] Elci L, Soylak M, Buyuksekarci EB, Anal. Sci., 19, 1621 (2003)