Synthesis of Polyketone Anion Ion Exchange Fibers by Paal-Knorr Reaction and Its Physico-Chemical Properties

Seong Yeon Hwang; Jeong Ju Kim; Eun Ji Park; Taek Sung Hwang

Macromolecular Research, Vol.28, No.5, 465-471, May, 2020

DOI10.1007/s13233-020-8058-4 Export Citation

Synthesis of Polyketone Anion Ion Exchange Fibers by Paal-Knorr Reaction and Its Physico-Chemical Properties

Seong Yeon Hwang, Jeong Ju Kim, Eun Ji Park, and Taek Sung Hwang^†

Department of Applied Chemical Engineering, College of Engineering, Chungnam National University, 99 Daehak-ro, Yuseoung-gu, Daejeon 34134, Korea

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In this study, polyketone anion exchange fibers were synthesized by the amination of polyketone via a Paal-Knorr reaction and a quaternization reaction. The amination reaction proceeded at different reaction times and amine N,N-dimethylethylene diamine (DME) concentrations. The ion exchange capacity (IEC) and water uptake (W.U.) increased with increasing amination reaction time and DME concentration, and the maximum IEC and W.U. were 1.03 meq/g and 19.2%, respectively. The tensile strength decreased significantly with increasing amination time and amine concentration. TGA showed that the thermal decomposition temperature of the fibers was 220 °C. The HCl gas adsorption properties of the aminated polyketone ion exchange fibers were evaluated, and the HCl gas removal efficiency remained at 100% in 40 min at 300 ppm.

Keywords:ion exchange fibers;paal-knorr reaction;amination;quaternization

[References]

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Cho IH, Kwak NS, Kang PH, Nho YC, Hwang TS, Polym. Korea, 30(3), 217 (2006)
Matsumoto H, Wakamatsu Y, Minagawa M, Tanioka A, J. Colloid Interface Sci., 293(1), 143 (2006)
Kabay N, Katakai A, Sugo T, Egawa H, J. Appl. Polym. Sci., 49, 599 (1993)
Soldatov VS, Izvest A, Nauk BSSR, Chem. Ser, 6, 39 (1982)
Soldatov VS, Kashinskii AV, Martinovich VI, Theor. Found. Chem. Eng., 44, 623 (2010)
Padungthon S, Greenleaf JE, Sengupta AK, Chem. Eng. Res. Des., 89(9A), 1891 (2011)
Guo JT, Ye YQ, Gao S, Feng YK, J. Mol. Catal. A-Chem., 307(1-2), 121 (2009)
Mul WP, Dirkzwager H, Broekhuis AA, Heeres HJ, van der Linden AJ, Orpen AG, Inorg. Chim. Acta, 327, 147 (2002)
Rivas BL, Pereira ED, Moreno-Villoslada I, Progr. Polym. Sci., 28, 173 (2003)
Kim YJ, Hwang CW, Hyeon SM, Canlier A, Hwang TS, Macromol. Res., 25(9), 898 (2017)
Ataollahi N, Vezzu K, Nawn G, Pace G, Cavinato G, Girardi F, Scardi P, Di Noto V, Di Maggio R, Electrochim. Acta, 226, 148 (2017)
Zhang YC, Broekhuis AA, Stuart MCA, Landaluce TF, Fausti D, Rudolf P, Picchioni F, Macromolecules, 41(16), 6141 (2008)
Mothana B, Boyr J, J. Molecular Structure: Theochem, 811, 97 (2007)
Pavia DL, Lampman GM, Kriz GS, Vyvyan JA, Introduction to Spectroscopy, 4th ed., Cengage Learning, Belmont, 2008.
Jung YS, Canlier A, Hwang TS, Polymer, 141, 102 (2018)
Tharun J, Hwang Y, Roshan R, Ahn S, Kathalikkattil AC, Park DW, Catalysis Sci. Technol., 2, 1674 (2012)
Koros WJ, Mahajan R, J. Membr. Sci., 175(2), 181 (2000)
Walker GM, Weatherley LR, Water Res., 31, 2093 (1997)
Sharafi K, Pirsaheb M, Gupta VK, Agarwal S, Moradi M, Vasseghian Y, Dragoi E, J. Mol. Liq., 274, 699 (2019)

[Referenced By]

[1] Liu RX, Guo JL, Tang HX, J. Colloid Interface Sci., 248(2), 268 (2002)

[2] Cho IH, Kwak NS, Kang PH, Nho YC, Hwang TS, Polym. Korea, 30(3), 217 (2006)

[3] Matsumoto H, Wakamatsu Y, Minagawa M, Tanioka A, J. Colloid Interface Sci., 293(1), 143 (2006)

[4] Kabay N, Katakai A, Sugo T, Egawa H, J. Appl. Polym. Sci., 49, 599 (1993)

[5] Soldatov VS, Izvest A, Nauk BSSR, Chem. Ser, 6, 39 (1982)

[6] Soldatov VS, Kashinskii AV, Martinovich VI, Theor. Found. Chem. Eng., 44, 623 (2010)

[7] Padungthon S, Greenleaf JE, Sengupta AK, Chem. Eng. Res. Des., 89(9A), 1891 (2011)

[8] Guo JT, Ye YQ, Gao S, Feng YK, J. Mol. Catal. A-Chem., 307(1-2), 121 (2009)

[9] Mul WP, Dirkzwager H, Broekhuis AA, Heeres HJ, van der Linden AJ, Orpen AG, Inorg. Chim. Acta, 327, 147 (2002)

[10] Rivas BL, Pereira ED, Moreno-Villoslada I, Progr. Polym. Sci., 28, 173 (2003)

[11] Kim YJ, Hwang CW, Hyeon SM, Canlier A, Hwang TS, Macromol. Res., 25(9), 898 (2017)

[12] Ataollahi N, Vezzu K, Nawn G, Pace G, Cavinato G, Girardi F, Scardi P, Di Noto V, Di Maggio R, Electrochim. Acta, 226, 148 (2017)

[13] Zhang YC, Broekhuis AA, Stuart MCA, Landaluce TF, Fausti D, Rudolf P, Picchioni F, Macromolecules, 41(16), 6141 (2008)

[14] Mothana B, Boyr J, J. Molecular Structure: Theochem, 811, 97 (2007)

[15] Pavia DL, Lampman GM, Kriz GS, Vyvyan JA, Introduction to Spectroscopy, 4th ed., Cengage Learning, Belmont, 2008.

[16] Jung YS, Canlier A, Hwang TS, Polymer, 141, 102 (2018)

[17] Tharun J, Hwang Y, Roshan R, Ahn S, Kathalikkattil AC, Park DW, Catalysis Sci. Technol., 2, 1674 (2012)

[18] Koros WJ, Mahajan R, J. Membr. Sci., 175(2), 181 (2000)

[19] Walker GM, Weatherley LR, Water Res., 31, 2093 (1997)

[20] Sharafi K, Pirsaheb M, Gupta VK, Agarwal S, Moradi M, Vasseghian Y, Dragoi E, J. Mol. Liq., 274, 699 (2019)