화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.88, 186-195, August, 2020
DOI10.1016/j.jiec.2020.04.012  Export Citation
Enhanced photocatalytic capacity of ZnS-ZnO-Sm2O3 composites for the removal of dyes and antibiotics in visible light region
Xiaogang Zheng1, 2, Fuyan Kang2, Congying Huang2, Sihao Lv1, †, Jinyang Zhang2, and Hao Peng3, †
  • 1Research Center for Eco-Environmental Engineering, Dongguan University of Technology, Dongguan Guangdong 523808, China
  • 2College of Chemistry and Chemical Engineering, Neijiang Normal University, Neijiang Sichuan 641100, China
  • 3College of Chemistry and Chemical Engineering, Yangtze Normal University, Chongqing 408100, China
E-mail:,
ZnS-ZnO-Sm2O3 (Zn-Sm-XY) composites were prepared via the high-temperature calcination of coreshell structured ZnS@Sm2O3 for the enhanced photocatalytic degradation of dyes and antibiotics in visible light region. Effects of calcined temperature, Sm2O3 content, pH value, contaminant concentration, and inorganic ions on the photocatalytic activity were investigated. Ternary Zn.Sm composites exhibit the excellent photocatalytic activity for the visible light driven degradation of tetracycline hydrochloride. Among these composites, Zn-Sm-2B prepared via the heat-treatment of ZnS-Sm2O3 at 673 K shows the best photocatalytic activity for the removal of tetracycline hydrochloride. The enhanced photocatalytic activity of Zn.Sm.2B is also achieved for the visible light driven degradation of methyl orange, methylene blue, and rhodamine B within 20 min. In addition, Zn-Sm-6C calcined from Zn-Sm-C at 1073 K as well as Zn-Sm-2B exhibits excellent photocatalytic activity. ㆍOH and ㆍO2 - radicals are vital for the enhanced photocatalytic activity of Zn-Sm-2B and Zn-Sm-2B in visible light region, respectively. The lattice defects, sulfur vacancies, and oxygen vacancies facilitate the efficient charge transfer and the rapid separation of electron-hole pairs at the junction interface of Zn-Sm-2B.
Keywords:ZnS-ZnO-Sm2O3;High-temperature calcination;Interface effect;Tetracycline degradation;Dyes removal
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