Ethylenediamine-incorporated MIL-101(Cr)-NH2 metal-organic frameworks for enhanced CO2 adsorption

The Ky Vo; Woo-Sik Kim; Jinsoo Kim

Korean Journal of Chemical Engineering, Vol.37, No.7, 1206-1211, July, 2020

DOI10.1007/s11814-020-0548-8 Export Citation

Ethylenediamine-incorporated MIL-101(Cr)-NH2 metal-organic frameworks for enhanced CO2 adsorption

The Ky Vo, Woo-Sik Kim¹, and Jinsoo Kim^{1, †}

Department of Chemical Engineering, Industrial University of Ho Chi Minh City, Ho Chi Minh City, 12 Nguyen Van Bao, Go Vap, Ho Chi Minh City, Vietnam
¹Department of Chemical Engineering, Kyung Hee University, 1732 Deogyeong-daero, Giheung-gu, Yongin-si, Gyeonggi-do 17104, Korea

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Ethylenediamine (EA)-incorporated MIL-101(Cr)-NH2 adsorbents were prepared for CO2 adsorption. First, MIL-101(Cr)-NH2 was directly prepared by the solvothermal method, followed by the EA incorporation inside the pores of MIL-101(Cr)-NH2. The prepared samples were characterized by N2 porosimetry, field-emission scanning electron microscopy, transmission electron microscopy, Fourier transform infrared spectrometry, thermogravimetric, and powder X-ray diffraction analyses. The effects of ethylenediamine loading in MIL-101(Cr)-NH2 on the CO2 adsorption capability were systematically investigated. EA-incorporated MIL-101(Cr)-NH2 showed CO2 adsorption capacity of ca. 3.4mmol/g, which was ~62% higher than the pristine MIL-101(Cr)-NH2. In addition, the amine-grafted MOF samples showed good regenerability and stability after consecutive adsorption-desorption cycles at ambient conditions. These suggest that introduction of alkylamine molecules into the pores of metal-organic frameworks can be a promising strategy to improve the CO2 soprtion ability of MOFs.

Keywords:MOFs;MIL-101(Cr)-NH2;Ethylenediamine@MIL-101(Cr)-NH2;CO2 Adsorption

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Yan Q, Lin Y, Kong C, Chen L, Chem. Commun., 49, 6873 (2013)
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[4] DeCoste JB, Peterson GW, Schindler BJ, Killops KL, Browe MA, Mahle JJ, J. Mater. Chem. A., 1, 11922 (2013)

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[9] Janakiraman N, Johnson M, Rom. J. Biophys., 25, 131 (2015)

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[11] Kuwahara Y, Kang DY, Copeland JR, Brunelli NA, Didas SA, Bollini P, Sievers C, Kamegawa T, Yamashita H, Jones CW, JACS, 134, 10757 (2012)

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[17] Liu J, Thallapally PK, McGrail BP, Brown DR, Liu J, Chem. Soc. Rev., 41, 2308 (2012)

[18] Ma X, Wang X, Song C, JACS, 131, 5777 (2009)

[19] McDonald TM, D'Alessandro DM, Krishna R, Long JR, Chem. Sci., 2, 2022 (2011)

[20] Mei L, Jiang T, Zhou X, Li YW, Wang HH, Li Z, Chem. Eng. J., 321, 600 (2017)

[21] Park HJ, Suh MP, Chem. Sci., 4, 685 (2013)

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[25] Wen M, Mori K, Kamegawa T, Yamashita H, Chem. Commun., 50, 11645 (2014)

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