화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.28, No.6, 573-579, June, 2020
DOI10.1007/s13233-020-8073-5  Export Citation
Ultrahigh Energy Storage Capacitance and High Breakdown Strength in Biaxially Oriented Poly(vinylidene fluoride) Using a High-Electric-Induced Technique
Hongwei Lu1, Jianxin Du1, Cuiping Yu1, Xingping Wang2, Yanlin Gao2, Weizhong Xu3, Aiping Liu3, Xiaoxiao Lu11, and Yingxin Chen1, 4, †
  • 1College of Materials & Environmental Engineering, Hangzhou Dianzi University, Hangzhou 310018, P. R. China
  • 2Engineering Technology Research Center of Fluoro-material, Quzhou 324004, P. R. China
  • 3Nanometer Measurement Laboratory, Center for Optoelectronics Materials and Devices, Zhejiang Sci-Tech University, Hangzhou 310018, P. R. China
  • 4Key Laboratory of Optoelectronic Chemical Materials and Devices, Ministry of Education, School of Chemical and Environmental Engineering, Jianghan University, Wuhan 430056, P. R. China
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The development of high dielectric materials with high energy densities is a crucial research domain in the modern microelectronics and power systems. The objective of this work was to develop the highly ordered crystal orientations and large ferroelectric crystalline β/γ-phases in the biaxially oriented poly(vinylidene fluoride) (BOPVDF). Importantly, a high discharged energy density and high dielectric constant was achieved by using a high-electric-induced technique. A suitable poling electric field was applied to the BOPVDF films in order to enhance the breakdown strength. Remarkably, the BOPVDF film poled at the electric field of 113 MV m-1 achieved an unprecedented discharged energy density of 25.4 J cm-3 at an ultra-high electric field of 550 MV m-1, which is by far the highest value ever achieved in flexible polymer-based capacitor films. Comparatively, the unpoled BOPVDF and commercial biaxially oriented polypropylene (BOPP) exhibited only a discharged energy density of 7.9 J cm-3 and 1.2 J cm-3, respectively. This systematic study provides a new design paradigm to exploit PVDF-based dielectric polymers for capacitor applications.
Keywords:biaxially oriented poly(vinylidene fluoride);high electric poling;high power-density capacitor;dielectric constant;ferroelectric crystalline phase
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