Journal of the Electrochemical Society, Vol.144, No.3, 948-955, 1997
The Low Current Domain of the Aluminum/Sulfur Battery
A variety of factors including solution-phase modification, aluminum composition, temperature, and anolyte volume, modify anodic behavior in the approach to the low current density domain of the aluminum/sulfur battery. A relatively low level [0.4% Hg(NO3)(2) by weight in the anolyte] of mercury provides an amalgram film on the aluminum anode which minimizes the parasitic chemical consumption of aluminum anode which aluminum, providing anodic faradaic efficiencies in excess of 80%. Anodic overpotential losses are high for aluminum immersed in mercury-containing electrolytes. However, at lower current densities, their absolute magnitude is several hundred millivolts or smaller and does not substantially impair the cell potential. Aluminum/sulfur battery discharge times up to several hundred hours are demonstrated for 0.2 mA/cm(2) current density cells.
Keywords:PHOTOELECTROCHEMICAL SOLAR-CELLS;AIR BATTERIES;ALKALINE-SOLUTIONS;ALLOY ANODES;POLYSULFIDE;ELECTROLYTE;SOLUBILITY;CORROSION;ENERGY;POWER