Inorganic Chemistry, Vol.59, No.9, 5818-5822, 2020
Unique Two-Dimensional Indium Telluride Templated by a Rare Wheel-Shaped Heterobimetallic Mn/In Cluster
A new indium telluride, [Mn4.78In2.22(ea)(12)](n)[In9.79Mn0.21Te17](n) (where Hea = ethanolamine), containing unprecedented nonsupertetrahedral [In9.79Mn0.21Te21] units is the first example of a two-dimensional indium telluride framework templated by a rare high-nuclearity wheel-shaped heterometallic [Mn4.78In2.22(ea)(12)](4.)(22+) cluster. The photocurrent response and magnetic properties were investigated.