Highly porous, In-filled CoSb(3)skutterudite materials with an attractive thermoelectric figure of merit (ZT similar to 1) and corresponding dense samples were fabricated through the cost-effective method of reduction in oxides in dry hydrogen and the pulsed electric current sintering (PECS) method, respectively. The reduction process was described in detail using in situ thermogravimetric analysis of Co2O3, Sb(2)O(3)and In(NO3)(3)center dot 5H(2)O separately and in a mixture. Two methods to synthesise the same material were examined: (a) free sintering of an initially reduced powder and (b) PECS. The free-sintered materials with higher porosities (up to similar to 40%) exhibited lower values of electrical conductivity than the dense PECS samples (porosity up to similar to 5%), but the benefit of an even sixfold reduction in thermal conductivity resulted in higher ZT values. The theoretical values of thermal conductivity for various effective media models considering randomly oriented spheroid pores are in good agreement with the experimental thermal conductivity data. The assumed distribution and shape of the pores correlated well with the scanning electron microscope analysis of the microstructure. The lowest value of thermal conductivity, equal to 0.5 W/m K, was measured at 523 K for In(0.1)Co(4)Sb(12)with 41% porosity. The highest value of ZT(max) = 1.0 at 673 K was found for the In(0.2)Co(4)Sb(12)sample in which the porosity was 36%. Graphic abstract