High-level quantum chemical approaches are performed to study the stability and electronic structure of tri-, di-, monocationic, and neutral scandium ammonia complexes. The calculated binding energies of all Sc(NH3)(1-8)(3+,2+,+,0) complexes reveal the higher stability of hexa- and octacoordinated systems. The ground states of Sc(NH3)(6,8)(2+) and Sc(NH3)(6,8) have a Sc2+(3d(1)) center, while there are two competitive electronic states for Sc(NH3)(6,8)(+) with a Sc2+(3d(1)) or a Sc3+ center. The remaining electrons occupy an outer diffuse s-type orbital (1s). The lower lying states involve 3d-3d transitions for Sc(NH3)(6,8)(2+) but outer 1s-1p transitions for Sc(NH3)(6,8)(+,0). The addition of one electron to Sc(NH3)(6,8)(3+,2+,+) reduces the binding energies but shortens the Sc-N bond lengths. The comparison with the vanadium and yttrium ammonia complexes (studied earlier) reveal the unique identity of scandium balancing between a d- and s-block element.