Coordination compounds of titanium(IV), zirconium(IV), and vanadium(V) with chiral salen ligands have been obtained and characterized, and their catalytic activity in the polymerization reaction of ethylene has been studied. It has been shown that in the presence of polymethylaluminoxane as a cocatalyst, the activity of the titanium-containing catalyst system reaches 944 kgPE mol(Ti)(-1) h(-1) and leads to the preparation of ultrahigh-molecular-weight polyethylene.