A process to upgrade a biogas product to biomethane has been investigated. Recycling of an absorbent is important for low-cost upgrading of biogas by chemical absorption. This study investigated the alkaline recovery of absorbent solution by thermal decomposition at various temperatures (75, 85 and 95 degrees C) and various vacuum levels (0.2, 0.4 and 0.6 bar). During heating, CO2 and H2S were released from the absorbent solution, which increased the pH. The highest pH 10.58 was reached for NaHCO3 solution from initial pH 8.86 when treated at 95 degrees C and 0.6 bar vacuum level (gauge pressure). The mass fraction of CO32- in the solution increased from 0.06 to 0.78. Experiments on H2S removal from NaHS solution gave the highest pH 10.38 at 95 degrees C and 0.6 bar vacuum pressure. Moreover, the performance of the recovered alkaline solution was tested in biogas absorption. The results show that CO2 and H2S removal efficiencies of alkaline solution before and after recovery were similar, at 80 and 99 % respectively. This study demonstrated that thermal decomposition has high potential for recovering the alkaline used absorbent, for recirculation back into the absorption process. (C) 2020 Institution of Chemical Engineers. Published by Elsevier B.V. All rights reserved.