Maleated Natural Rubber로 조절된 Natural Rubber/Halloysite 나노 튜브 복합재료

Nabil Hayeemasae; Kannika Sahakaro; Hanafi Ismail

Polymer(Korea), Vol.44, No.5, 596-602, September, 2020

DOI10.7317/pk.2020.44.5.596 Export Citation

Maleated Natural Rubber로 조절된 Natural Rubber/Halloysite 나노 튜브 복합재료

Maleated Natural Rubber Compatibilized Natural Rubber/Halloysite Nanotubes Composites

Nabil Hayeemasae^†, Kannika Sahakaro, and Hanafi Ismail¹

Department of Rubber Technology and Polymer Science, Faculty of Science and Technology, Prince of Songkla University, Pattani Campus, 94000, Pattani, Thailand
¹School of Materials and Mineral Resources Engineering, Engineering Campus, Universiti Sains Malaysia, 14300, Nibong Tebal, Penang, Malaysia

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The properties of rubber composites depend strongly on the compatibility of the rubber matrix and particulate filler. The polarity difference between the two phases has always been the main concern. Natural rubber (NR) and halloysite nanotubes (HNT) are one of the examples of the incompatible system. In this regard, a suitable compatibilizer is recommended to mediate the interactions. In this study, the maleated natural rubber (MNR) with various amounts of maleic anhydride (MA) was introduced as a compatibilizer to this composite. By increasing MA contents, scorch and curing times were increased whereas the maximum torque and the torque differences exhibited the highest values at the MA content of 2 phr. Payne effect was also implemented to monitor their rubber-filler interactions. The MNR with 2 phr of MA exhibited the lowest filler-filler interaction as shown by a lower decrement of storage modulus at high strain. This rubber composite also exhibited the optimum tensile and tear strengths. It is clearly highlighted that application of the MNR with a suitable MA amount enables to increase the rubber-filler interaction significantly and therefore improve a HNT dispersion. Hence, the use of MNR provided the great potential to compatibilize NR and HNT.

Keywords:natural rubber;maleated natural rubber;halloysite nanotubes;Payne effect

[References]

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Jovanovic V, Samarzija-Jovanovic S, Markovic G, Marinovic-Cincovic M, Budinski-Simendic J, KGK Kautschuk Gummi Kunststoffe, 9, 52 (2011)
Chakravarty S, Chakravarty A, Kautsch. Gummi Kunstst., 60, 619 (2007)
Ismail H, Pasbakhsh P, Fauzi MA, Bakar AA, Polym. Test, 27, 841 (2008)
Jia Z, Luo Y, Guo B, Yang B, Du M, Jia D, Polym. Plast. Technol. Eng., 48, 607 (2009)
Vahedi V, Pasbakhsh P, Chai SP, Mater. Des., 68, 42 (2015)
Song YH, Kim YJ, Kim HS, Polym. Korea, 43(6), 958 (2019)
Rooj S, Das A, Thakur V, Mahaling R, Bhowmick AK, Heinrich G, Mater. Des., 31, 2151 (2010)
Paran SMR, Naderi G, Ghoreishy MHR, Appl. Surf. Sci., 382, 63 (2016)
Du M, Guo B, Lei Y, Liu M, Jia D, Polym., 49, 4871 (2008)
Pasbakhsh P, Ismail H, Fauzi MA, Bakar AA, Polym. Test, 28, 548 (2009)
Ismail H, Rusli A, Rashid AA, Polym. Test, 24, 856 (2005)
Nakason C, Kaesaman A, Supasanthitikul P, Polym. Test, 23, 35 (2004)
Pasbakhsh P, Churchman GJ, Keeling JL, Appl. Clay Sci., 74, 47 (2013)
Sahakaro K, Beraheng S, J. Appl. Polym. Sci., 109(6), 3839 (2008)
Nabil H, Ismail H, Azura A, J. Elastomers Plast., 43, 429 (2011)
Coran AY, J. Appl. Polym. Sci., 87(1), 24 (2003)
Rattanasom N, Saowapark TA, Deeprasertkul C, Polym. Test, 26, 369 (2007)
Payne A, Whittaker R, Rubber Chem. Technol., 44, 440 (1971)
Kaewsakul W, Sahakaro K, Dierkes WK, Noordermeer JW, Rubber Chem. Technol., 87, 291 (2014)
Rooj S, Das A, Stockelhuber KW, Wang DY, Galiatsatos V, Heinrich G, Soft Matter, 9, 3798 (2013)
Waesateh K, Saiwari S, Ismail H, Othman N, Soontaranon S, Hayeemasae N, Int. J. Polym. Anal. Charact., 23, 260 (2018)

[Referenced By]

[1] Arrighi V, McEwen I, Qian H, Prieto MS, Polym., 44, 6259 (2003)

[2] Jovanovic V, Samarzija-Jovanovic S, Markovic G, Marinovic-Cincovic M, Budinski-Simendic J, KGK Kautschuk Gummi Kunststoffe, 9, 52 (2011)

[3] Chakravarty S, Chakravarty A, Kautsch. Gummi Kunstst., 60, 619 (2007)

[4] Ismail H, Pasbakhsh P, Fauzi MA, Bakar AA, Polym. Test, 27, 841 (2008)

[5] Jia Z, Luo Y, Guo B, Yang B, Du M, Jia D, Polym. Plast. Technol. Eng., 48, 607 (2009)

[6] Vahedi V, Pasbakhsh P, Chai SP, Mater. Des., 68, 42 (2015)

[7] Song YH, Kim YJ, Kim HS, Polym. Korea, 43(6), 958 (2019)

[8] Rooj S, Das A, Thakur V, Mahaling R, Bhowmick AK, Heinrich G, Mater. Des., 31, 2151 (2010)

[9] Paran SMR, Naderi G, Ghoreishy MHR, Appl. Surf. Sci., 382, 63 (2016)

[10] Du M, Guo B, Lei Y, Liu M, Jia D, Polym., 49, 4871 (2008)

[11] Pasbakhsh P, Ismail H, Fauzi MA, Bakar AA, Polym. Test, 28, 548 (2009)

[12] Ismail H, Rusli A, Rashid AA, Polym. Test, 24, 856 (2005)

[13] Nakason C, Kaesaman A, Supasanthitikul P, Polym. Test, 23, 35 (2004)

[14] Pasbakhsh P, Churchman GJ, Keeling JL, Appl. Clay Sci., 74, 47 (2013)

[15] Sahakaro K, Beraheng S, J. Appl. Polym. Sci., 109(6), 3839 (2008)

[16] Nabil H, Ismail H, Azura A, J. Elastomers Plast., 43, 429 (2011)

[17] Coran AY, J. Appl. Polym. Sci., 87(1), 24 (2003)

[18] Rattanasom N, Saowapark TA, Deeprasertkul C, Polym. Test, 26, 369 (2007)

[19] Payne A, Whittaker R, Rubber Chem. Technol., 44, 440 (1971)

[20] Kaewsakul W, Sahakaro K, Dierkes WK, Noordermeer JW, Rubber Chem. Technol., 87, 291 (2014)

[21] Rooj S, Das A, Stockelhuber KW, Wang DY, Galiatsatos V, Heinrich G, Soft Matter, 9, 3798 (2013)

[22] Waesateh K, Saiwari S, Ismail H, Othman N, Soontaranon S, Hayeemasae N, Int. J. Polym. Anal. Charact., 23, 260 (2018)