화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.89, 250-256, September, 2020
DOI10.1016/j.jiec.2020.05.021  Export Citation
Silver nanoplate-pillared mesoporous nano-clays for surface enhanced raman scattering
Gyeong-Hyeon Gwak1, 2, Tetsuo Yamaguchi2, Min-Kyu Kim3, Jin Kuen Park4, †, and Jae-Min Oh2, †
  • 1Beamline Research Division, Pohang Accelerator Laboratory, Pohang University of Science and Technology, Pohang, Gyeongsangbukdo 37673, Republic of Korea
  • 2Department of Energy and Materials Engineering, Dongguk University-Seoul, Seoul 04620, Republic of Korea
  • 3Future Industries Institute, Division of Information Technology, Engineering and Environment, University of South Australia, Mawson Lake 5095 South Australia, Australia
  • 4Department of Chemistry, Hankuk University of Foreign Studies, Yongin, Gyeonggi-do 17035, Republic of Korea
E-mail:,
Due to characteristic properties of silver (Ag), Ag nanoparticles have attracted unprecedented attention in various scientific fields such as sensors, catalysts, antibacterial materials, and so on. To obtain tailor-made functionalities of Ag nanoparticles with desired physicochemical properties, proper fabrication process is needed to control their sizes, morphologies or arrangements by hybridization with different components, immobilization on solid struts, and etc. Herein, we suggest a facile synthetic route to obtain Ag-pillared mesoporous nanoclays through simultaneous crystal growth and arrangement of Ag nanoplates with the help of a 2-dimensional inorganic template. To obtain Ag-pillars, layered silver-thiolate self-assembly was exfoliated to monolayers (Ag precursor) and then in-situ hybridized with layered double hydroxide in a layer-by-layer manner. Through reductive calcination, silver thiolate transformed to Ag-pillars which grew in nanoplate morphology with well-arrangement in confined space of nanoclays. Crystal structure, morphology, and pore structure of Ag-pillars in nanoclays were systematically characterized. Surface enhanced Raman scattering effect of arranged Ag-pillars on metal oxide substrate obtained upon calcination was also investigated with rhodamine 6 G.
Keywords:Nanostructured materials;Layered structure;Silver nanoplate;Superlattice;Mesopore;Surface enhanced raman scattering
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