Single and binary adsorption of dyes from aqueous solutions using functionalized microcrystalline cellulose from cotton fiber

Hongjuan Bai; Junhang Chen; Xiangyu Zhou; Chengzhi Hu

Korean Journal of Chemical Engineering, Vol.37, No.11, 1926-1932, November, 2020

DOI10.1007/s11814-020-0621-3 Export Citation

Single and binary adsorption of dyes from aqueous solutions using functionalized microcrystalline cellulose from cotton fiber

Hongjuan Bai, Junhang Chen^†, Xiangyu Zhou, and Chengzhi Hu

Province Key Laboratory of Cereal Resource Transformation and Utilization, School of Chemistry and Chemical Engineering, Henan University of Technology, Zhengzhou 450001, P. R. China

E-mail:

Simultaneous removal of dyes in the effluents of printing and dyeing industries is challenging, and the mechanism of the co-adsorption of dyes is still unclear. In this context, a novel adsorbent based on microcrystalline cellulose from cotton fiber through a simplified chemical modification process was prepared. Methylene blue (MB) and neutral red (NR) were selected to investigate their adsorption/co-adsorption on such functionalized microcrystalline cellulose. The experimental adsorption results indicated that the adsorption quantity of both dyes was similar for the single solute. The kinetics of adsorption processes could be better described with the pseudo-second order models for both single and binary dye solutes. The results of the co-adsorption suggested that the extended Langmuir model could well predict equilibrium. The maximum adsorption capacity of MB and NR for the single systems was 115.2 and 83.2mg/g, respectively. Moreover, an antagonistic effect could be found in the binary dye solute. The obtained results revealed that the co-adsorption of dyes might be driven by hydrogen bonding, π-π stacking interaction as well as electrostatic interaction.

Keywords:Dyes;Cellulose-based Adsorbent;Microcrystalline Cellulose;Adsorption Mechanism;Co-adsorption

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[2] Mpatani FM, Aryee AA, Kani AN, Guo Q, Dovi E, Qu L, Li Z, Han R, Chemosphere, 259, 127439 (2020)

[3] Jain SN, Tamboli SR, Sutar DR, Jadhav SR, Marathe JV, Shaikh AA, Prajapati AA, J. Clean Prod., 252, 119778 (2020)

[4] Xiao W, Garba ZN, Sun S, Lawan I, Wang L, Lin M, Yuan Z, J. Clean Prod., 253, 119989 (2020)

[5] Islam MA, Ali I, Karim SMA, Firoz MSH, Chowdhury AN, Morton DW, Angove MJ, J. Water Process Eng., 32, 100911 (2019)

[6] Cavusglu FC, Akan S, Ari EA, Cetinkaya E, Colak E, Dastan GN, Deniz S, Erdem D, Koksal M, Korkmaz S, Onsekiz N, Orucoglu B, Ozkaya D, Uslu HB, Ynal C, Yildinz O, Ozkara-Aydinoglu S, Bayazit SS, Korean J. Chem. Eng., 36(11), 1915 (2019)

[7] Degermenci GD, Degermenci N, Ayvaoglu V, Durmaz E, Cakir D, Akan E, J. Clean Prod., 225, 1220 (2019)

[8] Sarabadan M, Bashiri H, Mousavi SM, Korean J. Chem. Eng., 36(10), 1575 (2019)

[9] Chen B, Zhao HN, Chen SJ, Long FX, Huang B, Yang BQ, Pan XJ, Chem. Eng. J., 356, 69 (2019)

[10] Zhou Q, Gong W, Xie C, Yang D, Ling X, Yuan X, Chen S, Liu X, J. Hazard. Mater., 185, 502 (2011)

[11] Humelnicu D, Lazar MM, Ignat M, Dinu IA, Dragan ES, Dinu MV, J. Hazard. Mater., 381, 120980 (2020)

[12] Pan Y, Xie H, Liu H, Cai P, Xiao H, Bioresour. Technol., 286, 121366 (2019)

[13] Januario EFD, Beluci NDL, Vidovix TB, Vieira MF, Bergamasco R, Vieira AMS, Process Saf. Environ. Protect., 134, 140 (2020)

[14] Homem NC, Beluci NDL, Amorim S, Reis R, Vieira AMS, Vieira MF, Bergamasco R, Amorim MTP, Appl. Surf. Sci., 486, 499 (2019)

[15] Ghaemi N, Safari P, J. Hazard. Mater., 358, 376 (2018)

[16] Abdulhameed AS, Mohammad AT, Jawad AH, J. Clean Prod., 232, 43 (2019)

[17] Bashiri H, Nesari S, Sarabadan M, Korean J. Chem. Eng., 37(2), 240 (2020)

[18] Liu Q, Li Y, Chen H, Lu J, Yu G, Moslang M, Zhou Y, J. Hazard. Mater., 382, 121040 (2020)

[19] Shirazi EK, Metzger JW, Fischer K, Hassani AH, Chemosphere, 234, 618 (2019)

[20] Yu D, Wang Y, Wu M, Zhang L, Wang L, Ni H, J. Clean Prod., 232, 774 (2019)

[21] Vijayalakshmi K, Devi BM, Latha S, Gomathi T, Sudha PN, Venkatesan J, Anil S, Int. J. Biol. Macromol., 104, 1483 (2017)

[22] Hussin MH, Pohan NA, Garba ZN, Kassim MJ, Rahim AA, Brosse N, Yemloul M, Fazita MRN, Haafiz MKM, Int. J. Biol. Macromol., 92, 11 (2016)

[23] Xiong JQ, Jiao CL, Li CM, Zhang DS, Lin H, Chen YY, Cellulose, 21, 3073 (2014)

[24] Goncalves JO, da Silva KA, Rios EC, Crispim MM, Dotto GL, de Almeida Pinto LA, Int. J. Biol. Macromol., 142, 85 (2020)

[25] Rong Y, Han R, Korean J. Chem. Eng., 36(6), 942 (2019)

[26] Mohamed EA, Selim AQ, Ahmed SA, Sellaoui L, Bonilla-Petriciolet A, Erto A, Li Z, Li Y, Seliem MK, Chem. Eng. J., 380, 12245 (2020)

[27] Hossain MA, Ngo HH, Guo WS, Nghiem LD, Hai FI, Vigneswaran S, Nguyen TV, Bioresour. Technol., 160, 79 (2014)

[28] Agarwal B, Balomajumder C, Thakur PK, Chem. Eng. J., 228, 655 (2013)

[29] Chen Q, Zheng JW, Zheng LC, Dang Z, Zhang LJ, Chem. Eng. J., 350, 1000 (2018)

[30] Li LJ, Liu FQ, Jing XS, Ling PP, Li AM, Water Res., 45, 1177 (2011)

[31] Deihimi N, Irannajad M, Rezai B, J. Environ. Manage., 227, 277 (2018)

[32] Wang B, Zhai YB, Wang TF, Li SH, Peng C, Wang ZX, Li CT, Xu BB, Bioresour. Technol., 274, 525 (2019)

[33] Wu ZB, Zhong H, Yuan XZ, Wang H, Wang LL, Chen XH, Zeng GM, Wu Y, Water Res., 67, 330 (2014)