화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.90, 178-189, October, 2020
DOI10.1016/j.jiec.2020.07.010  Export Citation
Preparation of magnetic metal-organic frameworks with high binding capacity for removal of two fungicides from aqueous environments
Jiping Ma†, Shuang Li, Gege Wu, Maryam Arabi1, Feng Tan2, Yafeng Guan3, Jinhua Li1, and Lingxin Chen1, †
  • School of Environmental & Municipal Engineering, State-Local Joint Engineering Research Center of Urban Sewage Treatment and Resource Recovery, Qingdao University of Technology, Qingdao 266033, China
  • 1CAS Key Laboratory of Coastal Environmental Processes and Ecological Remediation, Shandong Key Laboratory of Coastal Environmental Processes, Research Center for Coastal Environmental Engineering and Technology, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai 264003, China
  • 2Key Laboratory of Industrial Ecology and Environmental Engineering (MOE), School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024, China
  • 3CAS Key Laboratory of Separation Sciences for Analytical Chemistry, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
E-mail:,
A novel kind of Zr-based magnetic metal-organic frameworks (MMOFs) was prepared by immobilization of UiO-66 onto Fe3O4@SiO2 particles via an efficient one-pot solvothermal method. Subsequently, it was used for adsorptive removal of triclosan (TCS) and triclocarban (TCC) fungicides from aqueous environments by magnetic solid phase separation. Morphology and physical/chemical features of the MMOFs were fully characterized by XRD, SEM, TEM, FT-IR, and VSM etc., showing high specific surface area, appropriate functionality, and desirable magnetic property. Several main factors affecting the adsorption performances of TCS and TCC on the MMOFs were systematically investigated and optimized, such as pH value of water sample, amounts/types of adsorbent and salinity. Under the optimized conditions, short adsorption equilibrium time (only 25 min) and outstanding saturated adsorption capacities (476.27 and 602.40 mg·g-1 for TCS and TCC, respectively) were the remarkable superiorities of the MMOFs compared with that of most reported adsorbents. The MMOFs demonstrated excellent adsorption selectivity for TCS and TCC and anti-interference ability. Also, the reusability for at least 11 cycles was another major profit of the MMOFs that saved cost and prevented waste. Moreover, the MMOFs demonstrated satisfactory removal/purification ability for actual environmental water samples. These benefits propounded a promising outlook of employing the MMOFs for influential removal of pollutants with considerable reliability in the field of wastewater treatment.
Keywords:Fungicide;Metal-organic frameworks (MOFs);Magnetic separation;Adsorptive removal;Water treatment
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