화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.90, 379-388, October, 2020
DOI10.1016/j.jiec.2020.06.030  Export Citation
Palladium nanoparticles anchored polydopamine-coated graphene oxide/Fe3O4 nanoparticles (GO/Fe3O4@PDA/Pd) as a novel recyclable heterogeneous catalyst in the facile cyanation of haloarenes using K4[Fe(CN)6] as cyanide source
Hojat Veisi†, Taiebeh Tamoradi, Asra Rashtiani, Saba Hemmati, and Bikash Karmakar1, †
  • Department of Chemistry, Payame Noor University, Tehran, Iran
  • 1Department of Chemistry, Gobardanga Hindu College, 24-Parganas (North), India
E-mail:,
Pd(0) nanoparticles stabilized over polydopamine (PDA) capped magnetic GO/Fe3O4 nanocomposites (GO/Fe3O4@PDA/Pd) have been synthesized in variable Pd load following a post grafting approach. Pd has been reduced in situ by the functionalized PDA avoiding the use of external harsh reductant. The structural properties of the synthesized materials were studied by different analytical techniques like Field Emission Scanning electron microscopy (FESEM), Energy Dispersive X-ray Spectroscopy (EDX), High Resolution Transmission Electron Microscopy (HRTEM), Fourier Transformed Infrared (FT-IR) spectroscopy, Inductively Coupled Plasma Atomic Emission Spectroscopy (ICP-AES), Thermo Gravimetric Analysis (TGA), Powder X-Ray Diffraction (XRD) and X-ray Photoelectron Spectroscopy (XPS). The novel GO/Fe3O4@PDA/Pd(0) nanocomposite exhibited excellent performance as a reusable catalyst in the facile cyanation of aryl halides using K4[Fe(CN)6] as a low cost and safe cyanating agent. The aryl nitriles were obtained in good to excellent yields and the catalyst was recycled up to 13 times with minimal change in its catalytic activity.
Keywords:Magnetic nanoparticles;Post grafting;Stabilized Pd(0);Cyanation;K4[Fe(CN)6];Reusable;Leaching test
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