화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.37, No.12, 2179-2191, December, 2020
DOI10.1007/s11814-020-0628-9  Export Citation
Magnetic graphene oxide-biomass activated carbon composite for dye removal
Tan Yan Ying, Abdul Aziz Abdul Raman†, Mustapha Mohammed Bello1, and Archina Buthiyappan
  • Department of Chemical Engineering, Faculty of Engineering, University of Malaya, 50603 Kuala Lumpur, Malaysia
  • 1Centre for Dryland Agriculture, Bayero University, P.M.B. 3011, Kano State, Nigeria
E-mail:
A magnetic composite was synthesized using palm kernel shell-based activated carbon, graphene oxide (GO) and iron oxide. The morphology, textural properties, magnetic properties, crystal structure and functional groups of the composite were studied. The characterization shows the successful formation of the ternary composite with a high specific surface area (280.39m2/g) and abundant surface functional groups. The magnetic properties of the composite indicate a saturation magnetization of 33.72 emu/g, signifying that the composite can be easily separated with an external magnetic field. The performance of the composite was then investigated through the removal of an anionic azo dye, Acid Blue 113, from aqueous solution. The effect of initial pH of the solution, adsorbent dosage and adsorption contact time was studied. The composite achieved an adsorption capacity of 32.2mg/g and 96.3% dye removal. Effective dye removal was still achieved after five cycles of adsorption-regeneration, with the dye removal of 74% after the fifth cycle. The analyses of adsorption isotherm and kinetics show that the adsorption process fits pseudo-secondorder kinetic and Langmuir isotherm models, indicating a monolayer chemisorption process. The excellent adsorption performance and reusability of the composite and its magnetic separability signify its potential as an adsorbent for wastewater treatment.
Keywords:Adsorption;Modified Graphene Oxide;Iron Oxide;Palm Kernel Shell;Acid Blue 113
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