금형온도 조건에 따른 PPS 복합수지의 물리적 특성 변화 연구

엄찬혁; 정도현; 유승용; 이상선; 이현욱; 이평찬; 고윤기; 정선경; 하진욱; Chanhyuk Um; Dohyun Jung; Seung Yong Yu; Sang Sun Lee; Hyun Wook Lee; Pyoung-Chan Lee; Youn Ki Ko; Sun Kyoung Jeoung; Jin Uk Ha

Polymer(Korea), Vol.44, No.6, 798-803, November, 2020

DOI10.7317/pk.2020.44.6.798 Export Citation

금형온도 조건에 따른 PPS 복합수지의 물리적 특성 변화 연구

Study on Physical Properties of Polyphenylene Sulfide Composites with Variothermal Mold Temperatures

엄찬혁, 정도현¹, 유승용², 이상선³, 이현욱, 이평찬, 고윤기, 정선경, 하진욱^†

한국자동차연구원 소재기술연구본부
¹코프라
²인지컨트롤스
³엘케이지엘에스피

Chanhyuk Um, Dohyun Jung¹, Seung Yong Yu², Sang Sun Lee³, Hyun Wook Lee, Pyoung-Chan Lee, Youn Ki Ko, Sun Kyoung Jeoung, and Jin Uk Ha^†

Material Technology R&D Division, KATECH, 303 Pungse-ro, Cheonan, Chungnam 31214, Korea
¹R&D Center KOPLA CO., Ltd, 142 Sangduwon-gil, Hwasung, Gyeonggi 18586, Korea
²R&D Team INZI Controls CO., Ltd., 171 Gunjacheon-ro, Shiheung, Gyeonggi 15090, Korea
³LK GLSP, 62 Jeonggicha 1-ro, Younggang, Jeonnam 57055, Korea

E-mail:

초록

폴리페닐렌 설파이드(PPS) 수지는 용융온도가 290 °C 이상이며, 내화학특성이 매우 우수한 결정성 슈퍼 엔지니어링 플라스틱이다. 소재가 지닌 우수한 특성으로 금속소재를 대체할 수 있는 화학 소재로 주목받으면서 선진국에서는 관련된 많은 연구가 진행되고 있지만, 국내에서는 소재가 지닌 우수한 특성에도 불구하고 아직 다양한 연구가 진행되지 못하고 있다. 본 연구에서는 PPS 수지의 금형 온도조건 변화에 따라 달라지는 PPS의 결정화도를 분석하였으며, 결정화도에 따른 수지의 물성변화 경향을 분석하였다. PPS 소재를 적용한 부품의 금형온도에 따른 물성변화 값을 측정하여 시편 사출물과 강성 특성을 비교 분석하였다.

Polyphenylene sulfide (PPS) is well known semi-crystalline super engineering plastic which is having a very high melting temperature (above 290 °C) and strong chemical resistance. Research on replacing metallic materials with PPS is going on due to its superior properties. However, PPS is the material that does not have much attention in Korea as compared to the other developed countries. In this research, the crystallinity of the resin was influenced by the mold temperature, as a result, physical properties such as tensile strength, thermal properties were changed. Analyses were carried out with specimen and automotive molded part.

Keywords:polyphenylene sulfide;mold temperature;crystallinity;cooling control;super engineering plastics

[References]

Kim DW, Yoon JW, Park S, Kim K, Lee T, Int. J. Autom. Techn., 14, 955 (2013)
Park J, Lee J, Kim J, Ahn K, Trans. KSAE, 1, 123 (2013)
Ha JU, Jeoung SK, Lee PC, Hwang YJ, Nam BK, Han IS, Kwak SB, Lee JY, Polym. Korea, 39(1), 64 (2015)
Maier A, Schmidt R, Oswald-Tranta B, Schledjewski R, Materials, 7, 413 (2014)
Adams RD, Bacon DGC, J. Compos. Mater., 7, 402 (1973)
Qin G, Na J, Mu W, Tan W, Yang J, Ren J, Compos. Part B-Eng., 154, 43 (2018)
Grenvesse P, Bull. Soc. Chim. France, 17, 599 (1897)
Hilditch TP, J. Chem. Soc., 97, 2579 (1910)
Glass HB, Reid EE, J. Am. Chem. Soc., 51, 3428 (1928)
Jeong DY, Yoo SY, Jung CG, Lee J, Kim SH, Lee PC, Lee HW, Ha JU, Elastomers Compos., 54, 308 (2019)
Nohara LB, Nohara EL, Moura A, Goncalves JMRP. Costa ML, Rezede MC, Polimeros, 16, 104 (2006)
Park K, Kim YS, J. Polym. Eng., 29, 135 (2009)
Park DC, Park CW, Shin DH, Kim YH, Compos. Res., 31, 63 (2018)
Baek YM, Shin PS, Kim JH, Park HS, Kwon DJ, Park JM, Compos. Res., 30, 175 (2017)
Supaphol P, Spruiell J, J. Macromol. Sci. B, 39, 257 (2000)
Yoon KH, Shin DY, Kim YC, Polym. Korea, 36(2), 245 (2012)

[1] Kim DW, Yoon JW, Park S, Kim K, Lee T, Int. J. Autom. Techn., 14, 955 (2013)

[2] Park J, Lee J, Kim J, Ahn K, Trans. KSAE, 1, 123 (2013)

[3] Ha JU, Jeoung SK, Lee PC, Hwang YJ, Nam BK, Han IS, Kwak SB, Lee JY, Polym. Korea, 39(1), 64 (2015)

[4] Maier A, Schmidt R, Oswald-Tranta B, Schledjewski R, Materials, 7, 413 (2014)

[5] Adams RD, Bacon DGC, J. Compos. Mater., 7, 402 (1973)

[6] Qin G, Na J, Mu W, Tan W, Yang J, Ren J, Compos. Part B-Eng., 154, 43 (2018)

[7] Grenvesse P, Bull. Soc. Chim. France, 17, 599 (1897)

[8] Hilditch TP, J. Chem. Soc., 97, 2579 (1910)

[9] Glass HB, Reid EE, J. Am. Chem. Soc., 51, 3428 (1928)

[10] Jeong DY, Yoo SY, Jung CG, Lee J, Kim SH, Lee PC, Lee HW, Ha JU, Elastomers Compos., 54, 308 (2019)

[11] Nohara LB, Nohara EL, Moura A, Goncalves JMRP. Costa ML, Rezede MC, Polimeros, 16, 104 (2006)

[12] Park K, Kim YS, J. Polym. Eng., 29, 135 (2009)

[13] Park DC, Park CW, Shin DH, Kim YH, Compos. Res., 31, 63 (2018)

[14] Baek YM, Shin PS, Kim JH, Park HS, Kwon DJ, Park JM, Compos. Res., 30, 175 (2017)

[15] Supaphol P, Spruiell J, J. Macromol. Sci. B, 39, 257 (2000)

[16] Yoon KH, Shin DY, Kim YC, Polym. Korea, 36(2), 245 (2012)