화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.94, 465-471, February, 2021
DOI10.1016/j.jiec.2020.11.020  Export Citation
Highly hydroxide-conductive anion exchange membrane with PIL@MOF-assisted ion nanochannels
Jia Chen1, Mingming Guan1, Kai Li1, and Shaokun Tang1, 2, †
  • 1Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering & Technology, Tianjin University, Tianjin 300350, China
  • 2Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin University, Tianjin 300350, China
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A highly hydroxide-conducting anion exchange membrane with well-organized multi ion channels were fabricated via incorporating poly ionic liquids modified MIL101 (PIL@MIL101) into imidazolated poly (2,6-dimethyl-1,4-phenylene oxide) (ImPPO). 1-Vinyl-3-ethylimidzolium bromine was first immobilized in MIL101 cages via supercritical fluid impregnation method. Afterwards, the rigid-assisted ion nanochannels were constructed by in-situ polymerization of ionic liquids within the long-range ordered pores of MIL101. Meanwhile, PPO was functionalized by 1-ethyl-2-methyimidzolium to prepare comb-shaped ImPPO with enhanced microphase separation structure. Then the PIL@MIL101 was combined with ImPPO to fabricate hybrid anion exchange membrane with well-organized multiple ion channels. The OH- conductivity of the hybrid membrane significantly reached 138 mS/cm at 80 °C (176% higher than that of pristine membrane). Furthermore, the stability and mechanical properties of the hybrid membranes were remarkably enhanced. The excellent performances render the hybrid membrane a good candidate for the application in anion exchange membrane fuel cells.
Keywords:MIL101;Poly ionic liquids;Comb-shaped ImPPO;Anion exchange membrane;Hydroxide conductivity
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