화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.94, 482-488, February, 2021
DOI10.1016/j.jiec.2020.11.023  Export Citation
Synthesis of optically active chiral mesoporous molybdenum carbide film
Fusheng Zhang1, 2, Xintong Zheng1, 3, Cunli Wang1, Dongdong Wang1, Xingya Xue1, and Guangyan Qing1, 4, †
  • 1Key Laboratory of Separation Science for Analytical Chemistry, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, Liaoning 116023, PR China
  • 2University of Chinese Academy of Sciences, Beijing 100049, PR China
  • 3Pharmacy College, Dalian Medical University, Dalian, Liaoning 116044, PR China
  • 4Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), College of Chemistry, Nankai University, Tianjin 300071, PR China
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A chiral nematic mesoporous molybdenum carbide film (CN-Mo2C) was fabricated through the self-assembly of cellulose nanocrystal with peroxomolybdate. CN-Mo2C exhibits a tunable chiral nematic structure by varying the ratio of constituents, enabling a surface area of 210 m2 g-1. Importantly, it shows a typical chiroptical feature through polarized optical microscopy and circular dichroism spectral analysis. As it has an excellent conductivity of 2.4 × 10-2 S cm-1, we try to use CN-Mo2C in the electrocatalytic HER production, presenting an efficient H2 production capacity. It is a versatile synthetic strategy that can conveniently enable other large-area macroscopic chiral metal-based materials.
Keywords:Chirality;Cellulose nanocrystal;Molybdenum;Structural tuning;Chiroptical property
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