Application of polyethylenimine multi-coated adsorbent for Pd(II) recovery from acidic aqueous solution: batch and fixed-bed column studies

Su Bin Kang; Zhuo Wang; Sung Wook Won

Korean Journal of Chemical Engineering, Vol.38, No.3, 523-530, March, 2021

DOI10.1007/s11814-020-0716-x Export Citation

Application of polyethylenimine multi-coated adsorbent for Pd(II) recovery from acidic aqueous solution: batch and fixed-bed column studies

Su Bin Kang¹, Zhuo Wang¹, and Sung Wook Won^{1, 2, †}

¹Department of Ocean System Engineering, Gyeongsang National University, 2 Tongyeonghaean-ro, Tongyeong, Gyeongnam 53064, Korea
²Department of Marine Environmental Engineering, Gyeongsang National University, 2 Tongyeonghaean-ro, Tongyeong, Gyeongnam 53064, Korea

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PEI multi-coated PSBF (PEI-M-PSBF) with high adsorption efficiency and good reusability for Pd(II) recovery was prepared by a PEI multi-coating method. The results of FT-IR and FE-SEM showed that the PEI-M-PSBF was successfully prepared. Batch experiments were conducted to study the adsorption/desorption performance of PEIM-PSBF to Pd(II). The Langmuir and pseudo-second-order models were well suited for the batch experiment isotherm and kinetic data, respectively. The adsorption capacity of Pd(II) by Langmuir model was 327.14mg/g, and the initial adsorption rate of 3-PEI-PSBF was 37.19mg/g min. As a result, the increase in amine groups on the PEI-MPSBF surface through the PEI multi-coating directly influenced the adsorption amount of the biosorbent. The effects of initial concentration, bed column depth, and flow rate were determined in a column system and the breakthrough curves were detected by Thomas model. In addition, the recycle of the adsorbent was examined by multiple time performing adsorption/desorption cycles up to ten times in a fixed-bed column.

Keywords:Palladium;Polyethylenimine;Multi-coating;Recovery;Column Process

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[2] Morcali MH, Zeytuncu B, Int. J. Miner. Process., 137, 52 (2015)

[3] Yamada M, Gandhi MR, Shibayama A, Sci. Rep., 8, 1 (2018)

[4] Ramesh A, Hasegawa H, Sugimoto W, Maki T, Ueda K, Bioresour. Technol., 99(9), 3801 (2008)

[5] Fomina M, Gadd GM, Bioresour. Technol., 160, 3 (2014)

[6] Mao J, Won SW, Vijayaraghavan K, Yun YS, Bioresour. Technol., 100(3), 1463 (2009)

[7] Yun YS, Park D, Park JM, Volesky B, Environ. Sci. Technol., 35, 4353 (2001)

[8] Vijayaraghavan K, Yun YS, Biotechnol. Adv., 26, 266 (2008)

[9] Cho Chul-Woong, Kang Su Bin, Kim Sok, Yun Yeoung-Sang, Won Sung Wook, Chem. Eng. J., 302, 545 (2016)

[10] Beolchini F, Pagnanelli F, Toro L, Veglio F, Hydrometallurgy, 70, 101 (2003)

[11] Sun C, Song G, Chen L, Ren X, Chen C, J. Colloid Interface Sci., 580, 550 (2020)

[12] Zhao F, Yang Z, Wei Z, Spinney R, Sillanpaa M, Tang J, Tam M, Xiao R, Chem. Eng. J., 388, 124307 (2020)

[13] Kwame J, Lin S, Kumar A, Zhao Y, Choi JW, Song MH, Wei W, Kumar DH, Cho CW, Yun YS, J. Clean Prod., 252, 119389 (2020)

[14] Choi HA, Park HN, Won SW, J. Environ. Manage., 204, 200 (2017)

[15] Zhao F, Repo E, Song Y, Yin D, Hammouda SB, Chen L, Kalliola S, Tang J, Tam KC, Sillanpaa M, Green Chem., 19, 4816 (2017)

[16] Bo S, Luo J, An Q, Xiao Z, Wang H, Cai W, Zhai S, Li Z, J. Clean Prod., 250, 119585 (2020)

[17] Shahbazi A, Younesi H, Badiei A, Chem. Eng. J., 168(2), 505 (2011)

[18] Kim S, Choi YE, Yun YS, J. Hazard. Mater., 313, 29 (2016)

[19] Won SW, Park J, Mao J, Yun YS, Bioresour. Technol., 102(4), 3888 (2011)

[20] Won SW, Kim S, Kotte P, Lim A, Yun YS, J. Hazard. Mater., 263, 391 (2013)

[21] Fytianos K, Voudrias E, Kokkalis E, Chemosphere, 40, 3 (2000)

[22] Gandhi MR, Yamada M, Kondo Y, Shibayama A, Hamada F, J. Ind. Eng. Chem., 30, 20 (2015)

[23] Vincent T, Parodi A, Guibal E, React. Funct. Polym., 68, 1159 (2018)

[24] Sharma S, Rajesh N, J. Environ. Chem. Eng., 5, 1927 (2017)

[25] Sharma S, Barathi M, Rajesh N, Chem. Eng. J., 259, 457 (2015)

[26] Orgul S, Atalay U, Hydrometallurgy, 67, 71 (2002)

[27] Hubicki Z, Wawrzkiewicz M, Wolowicz A, Chem. Analityczna, 53, 759 (2008)