화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.96, 82-97, April, 2021
DOI10.1016/j.jiec.2020.12.022  Export Citation
Promotional effects of CO2 on the oxidative dehydrogenation of propane over mesoporous VOX/γAl2O3 catalysts
Majid Lasisi Balogun1, Sagir Adamu1, Mohammed S. Ba-Shammakh1, and Mohammad M. Hossain1, 2, †
  • 1Department of Chemical Engineering, King Fahd University of Petroleum and Minerals, Dhahran, Saudi Arabia
  • 2Center of Research Excellence in Nanotechnology, King Fahd University of Petroleum and Minerals, Dhahran, Saudi Arabia
E-mail:
CO2 assisted oxidative dehydrogenation (ODH) propane to propylene over fluidizable mesoporous VOx/ La2O3-gAl2O3 catalysts has been investigated. The mixed oxide of La2O3 and gAl2O3 were synthesized by the co-precipitation technique and VOx was deposited on the supports by an incipient wetness impregnation approach. The prepared catalysts were characterized by various physicochemical characterizations to establish the desired properties of the catalysts. The H2-TPR indicated the supported VOx reduced in a single stage, indicating the formation of a homogeneous specie. Both the acidity and surface area of the catalysts decreased with increase of La content, as confirmed by the NH3-TPD and BET analysis, respectively. The CO2 assisted ODH of propane experiments were developed in a fluidized CREC Riser Simulator at 520-600 °C. The introduction of CO2 significantly enhanced both the propane conversion and propylene selectivity. Among the studied catalysts, VOx/γ-Al2O3 catalyst showed highest propylene yields (42.7%) at 550 °C.
Keywords:Oxidative dehydrogenation;Propane;Propylene;Mild oxidant;CO2
  1. Balogun ML, Adamu S, Bakare IA, Ba-Shammakh MS, Hossain MM, J. CO2 Util., 42, 101329 (2020)
  2. Sattler JJHB, Ruiz-Martinez J, Santillan-Jimenez E, Weckhuysen BM, Chem. Rev., 114(20), 10613 (2014)
  3. Wang Y, Li WC, Zhou YX, Lu R, Lu AH, Catal. Today, 339, 62 (2020)
  4. Zuo C, Wu M, Zhang XL, Guo QJ, Can. J. Chem. Eng., 99(1), 235 (2021)
  5. Long LL, Xia K, Lang WZ, Shen LL, Yang Q, Yan X, Guo YJ, J. Ind. Eng. Chem., 51, 271 (2017)
  6. Kim TH, Kang KH, Baek M, Song JH, Hong UG, Park DS, Choi WC, Park YK, Song IK, Mol. Catal., 433, 1 (2017)
  7. You R, Zhang XY, Luo LF, Pan Y, Pan HB, Yang JZ, Wu LH, Zheng XS, Jin YK, Huang WX, J. Catal., 348, 189 (2017)
  8. Natarajan P, Khan HA, Yoon SH, Jung KD, J. Ind. Eng. Chem., 63, 380 (2018)
  9. Bakare IA, Mohamed SA, Al-Ghamdi S, Razzak SA, Hossain MM, de Lasa HI, Chem. Eng. J., 278, 207 (2015)
  10. Setnicka M, Tisler Z, Kubicka D, Bulanek R, Top. Catal., 58(14-17), 866 (2015)
  11. Phongsawat W, Netiworaruksa B, Suriye K, Praserthdam P, Panpranot J, J. Ind. Eng. Chem., 20(1), 145 (2014)
  12. Nawaz Z, Baksh F, Zhu J, Wei F, J. Ind. Eng. Chem., 19(2), 540 (2013)
  13. Haddad N, Bordes-Richard E, Hilaire L, Barama A, Catal. Today, 126(1-2), 256 (2007)
  14. Chen KD, Bell AT, Iglesia E, J. Phys. Chem. B, 104(6), 1292 (2000)
  15. Putra MD, Al-Zahrani SM, Abasaeed AE, J. Ind. Eng. Chem., 18(3), 1153 (2012)
  16. Putra MD, Al-Zahrani SM, Abasaeed AE, Catal. Commun., 26, 98 (2012)
  17. Xiao H, Zhang J, Wang P, Wang X, Pang F, Zhang Z, Tan Y, Catal. Sci. Technol., 6(13), 5183 (2016)
  18. Choi Y, Yi J, Baek J, Yun D, Yun HJ, ACS Catal., 2(9), 1893 (2012)
  19. Ren Y, Wang J, Hua W, Yue Y, Gao Z, J. Ind. Eng. Chem., 18(2), 731 (2012)
  20. Lei TQ, Cheng YH, Miao CX, Hua WM, Yue YH, Gao Z, Fuel Process. Technol., 177, 246 (2018)
  21. Nowicka E, Reece C, Althahban SM, Mohammed KMH, Kondrat SA, Morgan DJ, He Q, Willock DJ, Golunski S, Kiely CJ, Hutchings GJ, ACS Catal., 8(4), 3454 (2018)
  22. Jacquemin M, Beuls A, Ruiz P, Catalysis Today, vol. 157, Elsevier, p.462 2010.
  23. Taghavinezhad P, Haghighi M, Alizadeh R, Microporous Mesoporous Mater., 261, 63 (2018)
  24. Nayak SC, Shee D, Deo G, Catal. Lett., 136(3-4), 271 (2010)
  25. Wang G, Li C, Shan H, Wu W, Ind. Eng. Chem. Res., 52(37), 13297 (2013)
  26. Michorczyk P, Ogonowski J, Kustrowski P, Chmielarz L, Appl. Catal. A: Gen., 349(1-2), 62 (2008)
  27. Sandupatla AS, Ray K, Thaosen P, Sivananda C, Deo G, Catal. Today, 354, 176 (2020)
  28. Wang G, Zhang S, Zhu X, Li C, Shan H, J. Ind. Eng. Chem., 1 (2020).
  29. Iriondo A, Barrio VL, Cambra JF, Arias PL, Guemez MB, Navarro RM, Sanchez-Sanchez MC, Fierro JLG, Catal. Commun., 10(8), 1275 (2009)
  30. Bona S, Guillen P, Alcalde JG, Garcia L, Bilbao R, Chem. Eng. J., 137(3), 587 (2008)
  31. Jimenez-Lopez A, Rodriguez-Castellon E, Maireles-Torres P, Diaz L, Merida-Robles J, Appl. Catal. A: Gen., 218(1-2), 295 (2001)
  32. Madduluri VR, Nagaiah P, Prathap C, Gidyonu P, Raju BD, Rao KSR, J. Saudi Chem. Soc., 23(6), 678 (2019)
  33. Khadzhiev SN, Usachev NY, Gerzeliev IM, Kalinin VP, Kharlamov VV, Belanova EP, Kazakov AV, Kanaev SA, Starostina TS, Pet. Chem., 55(8), 640 (2015)
  34. Katta L, Thrimurthulu G, Reddy BM, Muhler M, Grunert W, Catal. Sci. Technol., 1(9), 1645 (2011)
  35. Liu BS, Rui G, Chang RZ, Au CT, Appl. Catal. A: Gen., 335(1), 88 (2008)
  36. Al-Sultan FS, Basahel SN, Narasimharao K, Fuel, 233, 796 (2018)
  37. Gao XT, Jehng JM, Wachs IE, J. Catal., 209(1), 43 (2002)
  38. Jeon N, Choe H, Jeong B, Yun Y, Catal. Today, 352, 337 (2020)
  39. Routray K, Reddy KRSK, Deo G, Appl. Catal. A: Gen., 265(1), 103 (2004)
  40. Frank K, Wolff T, Lorenz H, Seidel-Morgenstern A, Suchorski Y, Piorkowska M, Weiss H, J. Catal., 247(2), 176 (2007)
  41. Ferreira ML, Volpe M, J. Mol. Catal. A-Chem., 184(1-2), 349 (2002)
  42. Solsona B, Blasco T, Nieto JML, Pena ML, Rey F, Vidal-Moya A, J. Catal., 203(2), 443 (2001)
  43. Monaci R, Rombi E, Solinas V, Sorrentino A, Santacesaria E, Colon G, Appl. Catal. A: Gen., 214(2), 203 (2001)
  44. Barbero BP, Cadus LE, Hilaire L, Appl. Catal. A: Gen., 246(2), 237 (2003)
  45. Rossetti I, Fabbrini L, Ballarini N, Oliva C, Cavani F, Cericola A, Bonelli B, Piumetti M, Garrone E, Dyrbeck H, Blekkan EA, Forni L, J. Catal., 256(1), 45 (2008)
  46. Pieck CL, Banares MA, Fierro JLG, J. Catal., 224(1), 1 (2004)
  47. Ascoop I, Galvita VV, Alexopoulos K, Reyniers MF, Van der Voort P, Bliznuk V, Marin GB, J. Catal., 335, 1 (2016)
  48. Mazumder J, de Lasa HI, Fuel, 216, 101 (2018)
  49. Bakare IA, Adamu S, Qamaruddin M, Al-Bogami SA, Al-Ghamdi S, Hossain MM, Ind. Eng. Chem. Res., 58(25), 10785 (2019)
  50. Adamu S, Razzak SA, Hossain MM, J. Ind. Eng. Chem., 64, 467 (2018)
  51. Al-Ghamdi S, Volpe M, Hossain MM, de Lasa H, Appl. Catal. A: Gen., 450, 120 (2013)
  52. Adnan MA, Adamu S, Muraza O, Hossain MM, Process Saf. Environ. Protect., 116, 754 (2018)
  53. Amusa HK, Adamu S, Bakare IA, Arjah AS, Al-Bogami SA, Al-Ghamdi S, Razzak SA, Hossain MM, J. Ind. Eng. Chem., 89, 339 (2020)
  54. Ahmad AL, Koohestani B, Bhatia S, Ooi SB, Int. J. Appl. Ceram. Technol., 9(3), 588 (2012)
  55. Mitran G, Mako E, Redey A, Marcu IC, Comptes Rendus Chim., 15(9), 793 (2012)
  56. Li XY, Li D, Tian H, Zeng L, Zhao ZJ, Gong JL, Appl. Catal. B: Environ., 202, 683 (2017)
  57. Salinas D, Escalona N, Pecchi G, Fierro JLG, Fuel, 253, 400 (2019)
  58. Yang QQ, Hu P, Xiu NY, Lang WZ, Guo YJ, ChemistrySelect, 3(35), 10049 (2018)
  59. Rostom S, De Lasa HI, Ind. Eng. Chem. Res., 56(45), 13109 (2017)
  60. Bandaru H, Mahomed AS, Singh S, Friedrich HB, Mol. Catal., 460, 74 (2018)
  61. Alonso DM, Mariscal R, Moreno-Tost R, Poves MDZ, Granados ML, Catal. Commun., 8(12), 2074 (2007)
  62. Khatamian M, Oskoui MS, Sadeghi E, J. Phys. Chem. C, 121(12), 6650 (2017)
  63. Argyle MD, Chen KD, Bell AT, Iglesia E, J. Phys. Chem. B, 106(21), 5421 (2002)
  64. Sanchez-Sanchez MC, Navarro RM, Fierro JLG, Catal. Today, 129(3-4), 336 (2007)
  65. Siew KW, Lee HC, Khan MR, Gimbun J, Cheng CK, J. Energy Chem, 24(3), 366 (2015)
  66. Lu JC, Li XF, He SF, Han CY, Wan GP, Lei YQ, Chen R, Liu P, Chen KZ, Zhang L, Luo YM, Int. J. Hydrog. Energy, 42(6), 3647 (2017)
  67. Gomez DM, Gatica JM, Hernandez-Garrido JC, Cifredo GA, Montes M, Sanz O, Rebled JM, Vidal H, Appl. Catal. B: Environ., 144, 425 (2014)
  68. Alothman ZA, Materials (Basel), 2874 (2012).
  69. Khan MY, Al-Ghamdi S, Razzak SA, Hossain MM, de Lasa H, Mol. Catal., 443, 78 (2107)
  70. Al-Ghamdi SA, de Lasa HI, Fuel, 128, 120 (2014)
  71. Zhu R, Chatzidimitriou A, Bond JQ, J. Catal., 359, 171 (2018)
  72. Elbadawi AAH, Osman MS, Razzak SA, Hossain MM, J. Taiwan Inst. Chem. Eng., 61, 106 (2016)
  73. Wachs IE, Weckhuysen BM, Appl. Catal. A: Gen., 157(1-2), 67 (1997)
  74. Wachs IE, Catal. Today, 27(3-4), 437 (1996)
  75. Zhao BY, Xu XP, Ma HR, Sun DH, Gao JM, Catal. Lett., 45(3-4), 237 (1997)
  76. Wachs IE, Dalton Trans., 11762 (2013).
  77. Liu BS, Rui G, Chang RZ, Au CT, Appl. Catal. A: Gen., 335(1), 88 (2008)
  78. Topsøe NY, Pedersen K, Derouane EG, J. Catal., 70(1), 41 (1981)
  79. Cam LM, Huyen ND, Ha NN, J. Chem., 2 (2013)
  80. Adnan MA, Mohammed AAA, Binous H, Razzak SA, Hossain MM, Fuel, 263, 116670 (2020)
  81. Mazumder J, de Lasa HI, Appl. Catal. B: Environ., 168-169, 250 (2015)
  82. Zhou R, Cao Y, Yan S, Fan K, Appl. Catal. A: Gen., 236(1-2), 103 (2002)
  83. Kondratenko EV, Steinfeldt N, Baerns M, Phys. Chem. Chem. Phys., 8(13), 1624 (2006)
  84. Narasimharao K, Alshehri A, Fuel, 278, 118375 (2020)
  85. Zhang YW, Zhou YM, Liu H, Wang Y, Xu Y, Wu PC, Appl. Catal. A: Gen., 333(2), 202 (2007)
  86. Liu Q, Zhang M, Sun LB, Su HJ, Zou XH, Qi CX, Ind. Eng. Chem. Res., 58(32), 14695 (2019)
  87. Alotibi MF, Alshammari BA, Alotaibi MH, Alotaibi FM, Alshihri S, Navarro S, Fierro JLG, Catal. Surv. Asia, 1 (2020).
  88. Takahara I, Chang WC, Mimura N, Saito M, Catal. Today, 45(1-4), 55 (1998)
  89. Ogonowski J, Skrzynska E, Catal. Commun., 11(2), 132 (2009)
  90. Sun P, Lin S, Guo H, Su J, Shi L, Catal. Lett., 1, 3 (2020)
  91. Burri A, Hasib MA, Mo YH, Reddy BM, Park SE, Catal. Lett., 148(2), 576 (2018)
  92. Han ZF, Xue XL, Wu JM, Lang WZ, Guo YJ, Chin. J. Catal., 39(6), 1099 (2018)
  93. Botavina MA, Martra G, Agafonov YA, Gaidai NA, Nekrasov NV, Trushin DV, Coluccia S, Lapidus AL, Appl. Catal. A: Gen., 347(2), 126 (2008)
  94. Burri A, Hasib MA, Mo YH, Reddy BM, Park SE, Catal. Lett., 148(2), 576 (2018)
  95. Michorczyk P, Ogonowski J, Zenczak K, J. Mol. Catal. A-Chem., 349(1-2), 1 (2011)
  96. Michorczyk P, Zenczak-Tomera K, Michorczyk B, Wegrzyniak A, Basta M, Millot Y, Valentin L, Dzwigaj S, J. CO2 Util., 36, 54 (2020)
  97. Zhang F, Wu R, Yue Y, Yang W, Gu S, Miao C, Hua W, Gao Z, Microporous Mesoporous Mater., 145(1-3), 194 (2011)
  98. Chen M, Xu J, Liu YM, Cao Y, He HY, Zhuang JH, Fan KN, Catal. Lett., 124(3-4), 369 (2008)