화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.96, 397-403, April, 2021
DOI10.1016/j.jiec.2021.02.006  Export Citation
Ultra-fast and efficient calcium co-intercalation host enabled by hierarchically 3D porous carbon nanotemplates
Jin Hwan Kwak1, 2, Jong Chan Hyun2, Jae-Ho Park1, 3, Kyung Yoon Chung1, 4, Seung-Ho Yu5, Young Soo Yun6, †, and Hee-Dae Lim1, 4, †
  • 1Center for Energy Storage Research, Korea Institute of Science and Technology (KIST), Seoul, 02792, Republic of Korea
  • 2Department of Chemical and Biological Engineering, Korea University, Seoul, 02841, Republic of Korea
  • 3Department of Materials Science and Engineering, Korea University, Seoul 02841, Republic of Korea
  • 4Division of Energy & Environment Technology, KIST School, Korea University of Science and Technology, Seoul 02792, Republic of Korea
  • 5Department of Chemical and Biological Engineering, Korea University, 02841, Republic of Korea
  • 6KU-KIST Graduate School of Converging Science and Technology, Korea University, 145 Anam-ro, Seongbuk-gu, Seoul, 02841, Republic of Korea
E-mail:,
As promising candidates for next-generation batteries, calcium-ion batteries (CIBs) have attractedsignificant attention because of the lower cost and improved environmental friendliness of Ca metal relative to those of Li and their potential to deliver higher energy densities. However, their practical application has been limited by the lack of an appropriate electrode that can induce fast Ca cointercalation/deintercalation reactions while providing longer cycle life. In this study, we report bacterial cellulose (BC) with a highly graphitic-like ordered structure as a new and efficient co-intercalation host for multivalent Ca ions. The free-standing BC electrode with unique 3D porous morphology possessed ultra-fast co-intercalation kinetics, much faster than that for a commercial graphite electrode. In addition, we addressed the controversial issue of whether Ca co-intercalation truly occurs in the graphitic layer. It is demonstrated that the co-intercalation is directly dependent on the degree of carbon crystallinity by using various BC electrodes with different crystallinities at regular intervals. Finally, the effect of the ordering of the carbon stacking layer on the co-intercalation chemistry was electrochemically investigated.
Keywords:Ca batteries;Co-intercalation;Crystallinity;Carbonization;Carbon materials;Bacterial cellulose;3D structure
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