Polymer/conductive ceramic composites with high dielectric constant have become research hotspot of dielectric capacitor materials. However, the conductivity and dielectric loss increase when high dielectric constant is achieved. In order to reconcile high dielectric constant and low dielectric loss, in this study, poly (vinylidene fluoride) (PVDF)/chromium carbide (Cr2C3)/montmorillonite (MMT) ternary composite films were prepared by solution cast. Dielectric response based on interfacial polarization was improved and dielectric constant of composites was increased. MMT ceramic was used to suppress interface leakage current. Compared with PVDF/Cr2C3 composites, the conductivity and dielectric loss of ternary composites were reduced.