The volatile gas of Triethylamine (TEA) can cause environment pollution and lead to the serious hurt of the human respiratory system. Therefore, it is necessary to detect low concentrations of TEA in our daily lives rapidly. The hybrid of pine dendritic BiVO4/reduced graphene oxide (rGO) has been synthesized firstly by one step hydrothermal process. The gas sensing tests show that the 13.0 wt% rGO hybrid not only exhibits high response of 5.9 and rapid response of 11.4 s, but also exclusive selectivity and longterm stability to 10 ppm of TEA at the operating temperature of 180 degrees C. The formation of heterojunction and the incoporation of rGO are responsible for the improving sensing properties of the hybrid to TEA, the former results in reduction of the electron depletion layer at interface in hybrid, while the latter enhances the specific surface of the hybrid and accelerates the transfer of electrons. The research is expected to have wide application in the development of composite based gas sensors made of rGO/metal oxide semiconductors. (c) 2020 Published by Elsevier Inc.