화학공학소재연구정보센터
Journal of Vacuum Science & Technology A, Vol.13, No.4, 1867-1871, 1995
Thermal-Stimulated and Electron-Stimulated Chemistry of a Cyclotriphosphazene Lubricant on a Magnetic Disk with a Hard Carbon Overcoat
The thermal and;electron induced decomposition of a bis (4-fluorophenoxy)-tetrakis(3-tri-fluoromethylphenoxy)cyclotriphosphazene(code-named X-1P) lubricant on a magnetic disk are studied by temperature-programmed desorption spectroscopy, electron-stimulated desorption, and Anger electron spectroscopy. X-1P decomposes on the surface with a threshold temperature for dissociation at similar to 570 K, similar to 100 K lower than the thermal decomposition temperature of fluid molecules. Electron impact also damages X-1P molecules. Depending on the electron energies, dissociative ionization and dissociative electron attachment are both likely mechanisms for the electron-induced dissociation : The cross section for the dissociative electron attachment by 3 eV electrons is roughly 9x10(-18) cm(2). For both 8 and 25 eV electrons the cross sections are larger.