Journal of Colloid and Interface Science, Vol.585, 668-675, 2021
Flexible-templated imprinting for fluorine-free, omniphobic plastics with re-entrant structures
Hypothesis: Compared to vertical micro-pillars, re-entrant micro-structures exhibited superior omniphobicity for suspending liquids to Cassie-Baxter state. However, the existing re-entrant structures rely on complex multi-step deposition and etching procedures. The conventional, rigid-templated imprinting would instead damage the re-entrant structures. This leads to the question: is it possible to preserve the re-entrant curvatures by a flexible-templated imprinting? Experiments: We facilely imprinted the re-entrant structures on a plastic substrate using a flexible nylon mesh template. The effect of imprinting time (15-35 min), temperature (110-120 degrees C) and pressure (15-50 Bar) was investigated. To further improve the liquid-repellency and abrasion resistance, the silica nanoparticles (30-650 nm) along with epoxy resin binder (10 mg/mL) were pre-coated. Findings: A one-step imprinting is sufficient to fabricate the re-entrant structures by utilizing flexible nylon-mesh template, without damaging the imprinted structures after the demolding process. The pre-coated silica nanoparticles and epoxy resin (1) improved liquid repellency by introducing hierarchical surface structures (e.g. contact angle hysteresis of olive oil reduced > 10 degrees), and (2) acted as a protective layer against mechanical abrasion (omniphobicity maintained after 25 cycles, similar to 1.6 kPa sand paper abrasion). Additionally, the fluorine-free post-treatment was sufficient for the omniphobicity on the obtained plastic structures. (C) 2020 Elsevier Inc. All rights reserved.