A one-pot solvothermal strategy and subsequent calcination were proposed for fabricating a composite of NiO nanoparticles on hexagonal Ni-based metal-organic framework (Ni-MOF) (Ni-MOF@NiO). The prepared NiO nanoparticles on the hexagonal Ni-MOF not only improves the electrical conductivity and increases redox active sites, but also prevents the agglomeration of NiO nanoparticles. In particular, highly dispersed and small-sized NiO nanoparticles on the hexagonal Ni-MOF facilitates the migration of electrolyte ions, and the pseudocapacitive performance is evaluated through electrochemical measurements. At 0.5 A g(-1), the Ni-MOF@NiO composite shows a specific capacitance of up to 1192.7 F g(-1) and a high capacity retention (93.23% over 5000 cycles) in 3 M KOH. Moreover, the Ni-MOF@NiO nanoparticles and activated carbon are assembled into aqueous devices with a maximum energy density of 62.2 Wh kg(-1). These results indicate the potential of Ni-MOF@NiO composite as an electrode material for application in supercapacitors. Additionally, the method of synthesizing Ni-MOF@NiO in this study can be used to synthesize other MOF@metal oxide materials for electrochemical energy storage and other related applications. (C) 2020 Elsevier Inc. All rights reserved.