Layered double hydroxides (LDH) and their magnetic composites have been intensively investigated as recyclable high-capacity phosphate sorbents but with little attention to their stability as function of pH and phosphate concentration. The stability of a Fe3O4@SiO2-Mg3Fe LDH P sorbent as function of pH (5-11) and orthophosphate (P-i) concentration (1-300 mg P/L) was investigated. The composite has high adsorption capacity (approx. 80 mg P/g) at pH 5 but with fast dissolution of the LDH component resulting in formation of ferrihydrite as evidenced by Mossbauer spectroscopy. At pH 7 more than 60% of the LDH dissolves within 60 min, while at alkaline pH, the LDH is more stable but with less than 40% adsorption capacity as compared to pH 5. The high P-i sorption at acid to neutral pH is attributed to P-i bonding to the residual ferrihydrite. Under alkaline conditions P-i is sorbed to LDH at low P-i concentration while magnesium phosphates form at higher P-i concentration evidenced by solid-state P-31 MAS NMR, powder X-ray diffraction and chemical analyses. Sorption as function of pH and P-i concentration has been fitted by a Rational 2D function allowing for estimation of P-i sorption and precipitation. In conclusion, the instability of the LDH component limits its application in wastewater treatment from acid to alkaline pH. Future use of magnetic LDH composites requires substantial stabilisation of the LDH component. (C) 2020 Elsevier Inc. All rights reserved.