Diffusion is an important phenomenon involved in thermal processing, e.g., a Si diffusion in an (Al-Si)-KxAlyFz clad alloy during aluminum (Al-Mn) brazing, to be considered in this study. Specifically, the Si migration affects the amount of liquid metal available to form a mating surfaces' bond and further influences the solid substrate dissolution at the liquid-solid interface between (Al-Si)-KxAlyFz and Al-Mn. These events greatly impact the performance (e.g., joint formation) of the materials involved. To quantify theoretically the available liquid metal contributing to the subsequent joint formation, the diffusion process is in the first approximation divided into two evolving time segments, both before the onset of resolidification: 1. the solid-state Si diffusion prior the clad melting and 2. the liquid state Si diffusion after the clad melting. Of the two segments, the later has not been addressed in the available literature. The analysis of the sequence of the solid and liquid diffusion segments has been facilitated by performing a series of experimental benchmark studies. The Si solid diffusion across the clad-core interface has been monitored at 150 degrees C, 250 degrees C, 350 degrees C, 450 degrees C and 550 degrees C peak temperatures. Each dwell at the peak lasted for 10 min. For the study of the impact of liquid diffusion on the solid substrate, the experiments have been performed at the peak temperature of 600 degrees C with different heating rates, ranging from 1 to 60 degrees C/min. The joint formation process evolution has been modeled, and an excellent agreement with empirical data has been established. [GRAPHICS] .