A new Zn-containing infinite coordination polymer, Zn-ICP, functionalized with Ru(acac) 3 complex was designed and utilized as an efficient visible light photocatalyst for dye degradation in aqueous solutions. Incorporation of Ru(acac), not only extended the light absorption of the Zn-ICP to the visible region but also led to electron-hole separation. Upon visible light illumination, photoinduced electron transfer from excited state of Zn-ICP to Ru(acac)(3) occurred, resulting in electron-hole separation as indicated by photoluminescence and electrochemical impedance spectroscopy. The obtained Ru-Zn-ICP revealed enhanced visible light photocatalytic activity in degradation of organic pollutants compared to pristine Zn-ICP owing to photoinduced electron transfer in the Ru-Zn-ICP system and efficient separation of photogenerated electron-hole pairs. The prepared Ru-Zn-ICP photocatalyst was readily recycled without major loss of activity in the successive cycles.