Two new yellow emitting heteroleptic Ir(III) complexes are designed and synthesized for solution-processed yellow phosphorescent organic light-emitting diodes (PHOLEDs) with the amide-bridge core as main ligand and 2-phenylpyridine (ppy) as the ancillary ligand, named as bis[5-(2-ethylhexyl)-8-(trifluoromethyl)benzo[c][1,5]naphthyrid in-6(5)one](phenylpyridine)iridium(III) (Ir-1) and bis[5-(2-ethylhexyl)benzo[c][1,5naphthyridin-6(5H)one](phenylpyridi ne)iridium(III) (Ir-2).Ir-1andIr-2complexes emit bright yellow emission in dichloromethane solution at 298 K. The newly synthesized Ir(III) complexes reveals the higher quantum yields over 40% and relatively short triplet lifetimes (0.12-0.15 mu s), both which warrant to both complexes highly electroluminescence active materials. Both Ir(III) complexes were utilized as emitters for yellow solution-process PHOLEDs and obtained better performance. In particular, maximum external quantum efficiency (EQE(max)) and maximum current efficiency (CEmax) of of 13.38% and 39.54 cd A(-1)with the CIE (x,y) coordinates of (0.45, 0.53) was achieved forIr-1based yellow device. Furthermore, PHOLEDs withIr-2as an emitter attained EQE(max)of 11.71% and CE(max)of 37.60 cd A(-1)with good color purity.