Biogas is a valuable source of renewable energy produced from biodegradable organic materials via anaerobic digestion. The production of H-2 by sorption enhanced steam reforming (SESR) of biogas has been studied thermodynamic and experimentally. A Pd/Ni-Co catalyst and dolomite as CO2 sorbent were used. The effect of biogas composition (CH4/CO2 vol.%) on the process was evaluated at 600 and 650 degrees C in a fluidized bed reactor using biogas CO2 concentrations of 5-50 vol.%. During conventional biogas steam reforming (SR), high CH4 partial pressures in the feed favor the process, producing high H-2 concentrations. During biogas SESR, CO2 was effectively removed from the gas phase by the sorbent for all the biogas compositions, and it did not alter the process compared to pure methane. Steam methane reforming (SMR) and water-gas shift (WGS), together with carbonation, were the main reactions occurring during biogas SESR. Dry (or CO2) methane reforming did not occur under the conditions studied due to the relatively low temperature and the presence of steam. High H-2 purity (98.4 vol.%) and H-2 yield (91%) were experimentally obtained, pointing out the biogas SESR as a promising technology for the efficient production of high-purity, high-yield hydrogen from a renewable source. (C) 2020 Elsevier Ltd. All rights reserved.