화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.97, 180-187, May, 2021
DOI10.1016/j.jiec.2020.12.036  Export Citation
A water-stable europium-MOF as a multifunctional luminescent sensor for some inorganic ions and dichloromethane molecule
Zhengde Li, Zhiying Zhan, Yuejiao Jia, Zhang Li, and Ming Hu†
  • Inner Mongolia Key Laboratory of Chemistry and Physics of Rare Earth Materials, School of Chemistry and Chemical Engineering, Inner Mongolia University, Hohhot 010021, China
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Based on the ligand 2,2'-bipyridine-5,5'-dicarboxylic acid (H2bpdc), a luminescent Eu-MOF was successfully synthesized under solvothermal conditions, namely, [Eu(bpdc)1.5(H2O)2]n (1). The experimental explorations showed that compound 1 could not only detect Fe3+ and Cu2+ ions with high selectivity and recyclability, but also serve as an excellent selective sensing material for PO4 3- ion among some anions. Surprisingly, as an outstanding example of Ln-MOFs with fluorescence response to dichloromethane in aqueous solution, compound 1 could also behave as a functional probe with high sensitivity, selectivity, and recyclability. Meanwhile, the possible distinguishing mechanisms of compound 1 for above ions and CH2Cl2 molecule were further speculated.
Keywords:Luminescence sensor;Coordination polymer;Fe3+;Cu2+;PO4;3-;Dichloromethane
  1. Yuan S, Feng L, Wang K, Pang J, Bosch M, Lollar C, et al., Adv. Mater., 30, 170430 (2018)
  2. Lustig WP, Mukherjee S, Rudd ND, Desai AV, Li J, Ghosh SK, Chem. Soc. Rev., 46, 3242 (2017)
  3. Van Vleet MJ, Weng TT, Li XY, Schmidt JR, Chem. Rev., 118(7), 3681 (2018)
  4. Li H, Wang K, Sun Y, Lollar CT, Li J, Zhou HC, Mater. Today, 21, 108 (2018)
  5. Espallargas GM, Coronado E, Chem. Soc. Rev., 47, 533 (2018)
  6. Zhu L, Liu XQ, Jiang HL, Sun LB, Chem. Rev., 117(12), 8129 (2017)
  7. Huang YB, Liang J, Wang XS, Cao R, Chem Soc. Rev., 46, 126 (2017)
  8. Yi FY, Chen D, Wu MK, Han L, Jiang HL, ChemPlusChem, 81, 675 (2016)
  9. Jaros SW, Sokolnicki J, Wołoszyn A, Haukka M, Kirillov AM, Smolenski P, J. Mater. Chem. C, 6, 1670 (2018)
  10. Gu J, Liang X, Cui Y, Wu J, Shia Z, Kirillov AM, CrystEngComm, 19, 2570 (2017)
  11. He J, Xu J, Yin J, Li N, Bu XH, Sci. China Mater., 62, 1655 (2019)
  12. Gao RC, Guo FS, Bai NN, Wu YL, Yang F, Liang JY, Li ZJ, Wang YY, Inorg. Chem., 55(21), 11323 (2016)
  13. Cui Y, Chen B, Qian G, Coord. Chem. Rev., 273-274, 76 (2014)
  14. Zeng G, Xing SH, Wang XR, Yang YL, Ma DX, Liang HW, Gao L, Hua J, Li GH, Shi Z, Feng SH, Inorg. Chem., 55(3), 1089 (2016)
  15. Han ML, Xu GW, Li DS, Azofra LM, Zhao J, Chen B, Sun C, ChemistrySelect, 1, 3555 (2016)
  16. Yang LZ, Wang J, Kirillov AM, Dou W, Xu C, Fang R, Xua CL, Liu WS, CrystEngComm, 18, 6425 (2016)
  17. Wen GX, Wu YP, Dong WW, Zhao J, Li DS, Zhang J, Inorg. Chem., 55(20), 10114 (2016)
  18. Xu H, Fang M, Cao CS, Qiao WZ, Zhao B, Inorg. Chem., 55, 47900 (2016)
  19. Wu S, Min H, ShinW, Cheng P, Adv. Mater., 32, 180587 (2019)
  20. Yang YJ, Li YH, Liu D, Cui GH, CrystEngComm, 22, 1166 (2020)
  21. Zhan Z, Liang X, Zhang X, Jia Y, Hu M, Dalton Trans., 48, 1786 (2019)
  22. Bolisetty S, Peydayesh M, Mezzenga R, Chem. Soc. Rev., 48, 463 (2019)
  23. Yan Z, Hu L, You J, Anal. Methods, 8, 5738 (2016)
  24. Yang D, Lu L, Feng S, Zhu M, Dalton. Trans., 49, 7514 (2020)
  25. Zheng M, Tan H, Xie Z, Zhang L, Jing X, Sun Z, ACS Appl. Mater. Inter, 5, 1078 (2013)
  26. Udhayakumari D, Naha S, Velmathi S, Anal. Methods, 9, 552 (2017)
  27. Yang Y, Liu W, Cao J, Wu J, Food Chem., 328, 127119 (2020)
  28. Fang M, Zheng R, Wu Y, Yue D, Qian X, Zhao Y, Bian Z, Environ Sci-nano, 6, 105 (2019)
  29. Nakamura H, Anal. Methods, 2, 430 (2010)
  30. Chen X, Zhou G, Mao S, Chen J, Environ Sci-nano, 5, 837 (2018)
  31. Qin L, Wang X, Liu Y, Wei H, Anal. Chem., 90, 9983 (2018)
  32. Shestakova M, Sillanpaa M, Chemosphere, 93, 1258 (2013)
  33. Farahani YD, Safarifard V, J. Solid State Chem., 275, 31 (2019)
  34. Xia Y, Cao KL, Han MM, Feng YL, Inorg. Chem. Comm., 56, 76 (2015)
  35. Mo KQ, Ma XF, Wang HL, Zhu ZH, Liu YC, Zou HH, Liang FP, Sci. Rep., 9, 12231 (2019)
  36. Huang W, Pan FF, Liu Y, Huang SD, Li YJ, Yong J, Li Y, Kirillov AM, Wu DY, Inorg. Chem., 56(11), 6362 (2017)
  37. Gu JZ, Wen M, Cai Y, Shi ZF, Nesterov DS, Kirillova MV, Kirillov AM, Inorg. Chem., 58(9), 5875 (2019)
  38. Huang W, Jiang J, Wu DY, Xu J, Xue B, Kirillov AM, Inorg. Chem., 54(22), 10524 (2015)
  39. Li C, Zeng C, Chen Z, Jiang Y, Yao H, Yang Y, Wong WT, J. Hazard. Mater., 384, 121498 (2020)
  40. Pan H, Xu S, Ni Y, Sens. Actuators B-Chem., 283, 731 (2019)
  41. Das C, Upadhyay A, Ansari KU, Ogiwara N, Kitao T, Horike S, Shanmugam M, Inorg. Chem., 57(11), 6584 (2018)
  42. Zhou JM, Shi W, Xu N, Cheng P, Cryst. Growth Des., 13, 1218 (2013)
  43. Rath BB, Vittal JJ, Inorg. Chem., 59(13), 8818 (2020)
  44. Abha K, Nebu J, Anjali Devi JS, Aparna RS, Anjana RR, Aswathy AO, George S, Sens. Actuators B-Chem., 282, 300 (2019)
  45. Zhang Y, Yuan S, Day G, Wang X, Yang X, Zhou HC, Coord. Chem. Rev., 354, 28 (2018)
  46. Li B, Zhou J, Bai F, Xing Y, Dyes Pigment., 172, 107862 (2020)
  47. Dang S, Ma E, Sun ZM, Zhang H, J. Mater. Chem., 22, 16920 (2012)
  48. Luo J, Liu BS, Zhang XR, Liu RT, J. Mol. Struct., 1177, 444 (2019)
  49. Yu HH, Fan MY, Liu Q, Su ZM, Li X, Pan QQ, Hu XL, Inorg. Chem., 59(3), 2005 (2020)
  50. Duan L, Zhang C, Cen P, Jin X, Liang C, Yang J, Liu X, CrystEngComm, 22, 1695 (2020)
  51. Alammar I, Hlova Z, Gupta S, Balema V, Pecharsky VK, Mudring AV, Dalton Trans., 47, 7594 (2018)
  52. Rao PC, Mandal S, Inorg. Chem., 57(19), 11855 (2018)
  53. Du Y, Yang H, Liu R, Shao C, Yang L, Dalton Trans., 49, 13003 (2020)
  54. Zeng YN, Zheng HQ, He XH, Ca GJ, Wang B, Wu K, Lin ZJ, Dalton Trans., 49, 9680 (2020)
  55. Zhan Z, Jia Y, Li D, Zhang X, Hu M, Dalton Trans., 48, 15255 (2019)
  56. Zhang XJ, Su FZ, Chen DM, Peng Y, Guo WY, Liu CS, Du M, Dalton Trans., 48, 1843 (2019)
  57. Shi Y, Ye J, Qi Y, Akram MA, Rauf A, Ning G, Dalton Trans., 47, 17479 (2018)