화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.97, 515-522, May, 2021
DOI10.1016/j.jiec.2021.03.006  Export Citation
Visual colorimetric detection of ammonia under gaseous and aqueous state: Approach on cesium lead bromide perovskite-loaded porous electrospun nanofibers
Bumjun Park, Suheon Kim, Cheol Hwan Kwak, Kugalur Ranjith Shanmugam1, Young-Kyu Han1, †, Youngjin Cho2, †, and Yun Suk Huh†
  • NanoBio High-Tech Materials Research Center, Department of Biological Engineering, Inha University, 100 Inha-ro, Incheon, 22212, Republic of Korea
  • 1Department of Energy and Material Engineering, Dongguk University-Seoul, Seoul, 04620, Republic of Korea
  • 2Research Group of Consumer Safety, Korea Food Research Institute, 245 Nongsaengmyeong-ro, Iseo-myeon, Wanju-gun, Jeollabuk-do 55365, Republic of Korea
E-mail:, ,
In this work, we fabricate porous cesium lead bromide nanofibers (CsPbBr3 NFs) via electrospinning and employ them in a sensor to effectively detect both gaseous and aqueous ammonia. The CsPbBr3 NFs are produced by first mixing cesium lead bromide nanocrystals (CsPbBr3 NCs) with polystyrene (PS), followed by solidifying the mixture into NFs using electrospinning. Porous NFs are modified using the volatile solvent toluene, which is volatilized during the electrospinning process. The applicability of the proposed CsPbBr3 NFs for use under various environmental conditions is verified by analyzing their stability in response to changes in temperature, moisture level and pH, which are critical drawbacks of CsPbBr3 NCs. Gaseous ammonia (9 mg L-1) in an N2 carrier is subsequently detected using the photoluminescence (PL) properties of the CsPbBr3 NFs. In addition, an ammonia concentration of 100.0 mg L-1 in an aqueous solution can be detected using the PL intensity. Therefore, we believe that the proposed CsPbBr3 NFs show significant promise for use in detection sensors to assess the extent of food decay, allowing customers to purchase fresh agricultural products more safely.
Keywords:Cesium lead bromide;Perovskite;Polystyrene;Porous nanofibers;Electrospun;Nanofibers;Ammonia detection
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