화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.100, 112-118, August, 2021
DOI10.1016/j.jiec.2021.05.033  Export Citation
Low-cost and highly safe solid-phase sodium ion battery with a Sn-C nanocomposite anode
Hakgyoon Yu1, Kyu Seomoon2, Jeha Kim1, 2, and Jae-Kwang Kim1, 2, †
  • 1Department of Energy Convergence Engineering, Cheongju University, Cheongju, Chungbuk 28503, Republic of Korea
  • 2Division of Energy & Optical Technology Convergence, Energy & Applied Chemistry, Cheongju University, Cheongju, Chungbuk 28503, Republic of Korea
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With the use of a conducting ceramic-based solid-phase hybrid electrolyte, the batteries can maintain safe and stable operation during the reversible insertion/extraction of sodium ions by the suppression of sodium dendrites. Here, Sn-C nanocomposites are prepared by a simple one-pot synthesis process, and they have a unique structure in which nanosized Sn particles are embedded in an amorphous carbon host derived from sucrose. The Sn-C nanocomposite is used to fabricate a solid-phase sodium-ion battery with a Na3Zr2Si2PO12 ceramic-based hybrid solid electrolyte. The Sn-C-based solid-phase sodium battery shows high electrochemical performance with a high discharge capacity of 669.9 mA h g-1 at 0.2 C with a Coulombic efficiency close to 100%. The electrochemical alloy mechanism of the Sn-C nanocomposite is investigated by X-ray photoelectron spectroscopy. The good electrochemical performance demonstrates the advantages of using the Na3Zr2Si2PO12 ceramic-based hybrid solid electrolyte and Sn-C nanocomposite in solid-phase sodium ion batteries.
Keywords:Sn-C nanocomposite;Conducting ceramic;Hybrid solid-phase electrolyte;Sodium ion battery;Electrochemical performance
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