화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.101, 423-429, September, 2021
Chemically synthesized copper sulfide nanoflakes on reduced graphene oxide for asymmetric supercapacitors
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The present work describes the deposition of coppersulfide (Cu2S) nanoflakes onto reduced graphene oxide (rGO) on three dimensional (3D) nickel foam byinexpensive chemical methods. The nanohybrid structure exhibitedexcellent surface area (41.67 m2 g-1) with a porous structure (pore size 22.8 nm) and good electrical conductivity with a maximum specific capacitance of 1264 F g-1 at a scan rate of 5 mV s-1. The Cu2S@rGOcomposite exhibits a significantlyhigher specific capacitance. The nanohybrid structure showed outstandingcycling stability of 94 % after 10000cycles. The asymmetric supercapacitor (ASC) device, Cu2S@rGO//rGO exhibited a maximumspecific capacitance of 135 F g-1 withhighenergy and power densities of 50 Wh kg-1, and 7000 W kg-1, respectively.
  1. Wang E, Xiao S, Hou Y, Hu C, Liu L, Wu Y, RSC Adv., 3, 13059 (2013)
  2. ConwayB E, Bockris JOM, Ammar IA, Trans. Faraday Soc., 47, 756 (1951)
  3. Kotz R, Carlen M, Electrochim. Acta, 45(15-16), 2483 (2000)
  4. Long J, Belanger D, Brousse T, Sugimoto W, Sassin M, Crosnier O, MRS Bull., 36, 513 (2011)
  5. Wang R, Yan X, Lang J, Zhenga Z, Zhang P, J. Mater. Chem. A, 2, 12724 (2014)
  6. Zhang JT, Jiang JW, Li HL, Zhao XS, Energy Environ. Sci., 4, 4009 (2011)
  7. Xu K, Li W, Liu Q, Li B, An L, Chen Z, Zou R, Hu J, J. Mater. Chem. A, 2, 4795 (2014)
  8. Wang X, Sumboja A, Yan J, Lee P, Nanoscale, 4, 7266 (2012)
  9. Fan ZJ, Yan J, Wei T, Zhi LJ, Ning GQ, Li TY, Wei F, Adv. Funct. Mater., 21(12), 2366 (2011)
  10. Cheng YW, Zhang HB, Lu ST, Varanasi CV, Liu J, Nanoscale, 5, 1067 (2013)
  11. Liu Y, Zhang B, Yang Y, Chang Z, Wen Z, Wu Y, J. Mater. Chem. A, 1, 13582 (2013)
  12. Xiong G, Meng C, Reifenberger RG, Irazoqui PP, Fisher TS, Electroanal., 26(1), 30 (2014)
  13. Huang Y, Liang J, Chen Y, Small, 8, 1805 (2012)
  14. Zhao X, Sanchez BM, Dobson PJ, Grant PS, Nanoscale, 3, 839 (2011)
  15. Wang YG, Hong ZS, Wei MD, Xia YY, Adv. Funct. Mater., 22(24), 5185 (2012)
  16. Arico AS, Bruce P, Scrosati B, Tarascon JM, Van Schalkwijk W, Nat. Mater., 4(5), 366 (2005)
  17. Dunn B, Kamath H, Tarascon JM, Science, 334(6058), 928 (2011)
  18. PatilS J, BulakheR N, LokhandeC D, Chempluschem, 80, 1478 (2015)
  19. Jiang H, Zhao T, Li CZ, Ma J, J. Mater. Chem., 21, 3818 (2011)
  20. BulakheR N, NguyenV H, Shim JJ, New J. Chem., 41, 1473 (2017)
  21. Patil UM, Gurav KV, Fulari VJ, Lokhande CD, Joo OS, J. Power Sources, 188(1), 338 (2009)
  22. Jagadale AD, Kumbhar VS, Bulakhe RN, Lokhande CD, Energy, 64, 234 (2014)
  23. Patil BH, Bulakhe RN, Lokhande CD, J. Mater. Sci.: Mater. Electron., 25, 2188 (2014)
  24. Deshmukh PR, Bulakhe RN, Pusawale SN, Sartale SD, Lokhande CD, RSC Adv., 36, 28687 (2015)
  25. Gorai S, Ganguli D, Chaudhuri S, Cryst. Growth Des., 5, 875 (2005)
  26. Kalathil S, Nguyen VH, Shim JJ, Khan MM, Lee J, Cho MH, J. Nanosci. Nanotechno., 3, 7712 (2013)
  27. Bulakhe RN, Sahoo S, Nguyen TT, Lokhande CD, Roh CH, Lee YR, Shim JJ, RSC Adv., 6, 14844 (2016)
  28. Shi C, Dong H, Zhu R, Li H, Sun Y, Xu D, Zhao Q, Yu D, Nano Energy, 13, 670 (2015)
  29. Stevic Z, Rajcic-Vujasinovic M, J. Power Sources, 160(2), 1511 (2006)
  30. PathanH M, Lokhande CD, Bull. Mater. Sci., 27, 85 (2004)
  31. SartaleS D, Lokhande CD, Mat. Chem. Phys., 65, 63 (2000)
  32. Li ZJ, Yang BC, Lv XW, Li YC, Wang L, Appl. Surf. Sci., 370, 508 (2016)
  33. Peng C, Zhang S, Zhou X, Chen GZ, Energy Environ. Sci., 3, 1499 (2010)
  34. Kundu J, Pradhan D, Appl. Mater. Inter., 6, 1823 (2014)
  35. Wu Y, Wadia C, Ma W, Sadtler B, Alivisatos A, Nano Lett., 8, 2551 (2008)
  36. Tang H, He Y, Li B, Jung J, Zhang C, Liu X, Nanoscale, 7, 9731 (2015)
  37. Liu J, Huang X, Li Y, Sulieman KM, Heb X, Sun F, J. Mater. Chem., 16, 4427 (2006)
  38. Lamiel C, Nguyen VH, Roh C, Kang C, Shim JJ, Electrochim. Acta, 210, 240 (2016)
  39. Li C, Yu Z, Neff D, Zhamu A, Jang BZ, Nano Lett., 10(12), 4863 (2010)
  40. Eldin MSM, Elaassar MR, Elzatahry AA, Al-Sabah MMB, Arab. J. Chem., 10, 1153 (2017)
  41. Patil UM, Sohn JS, Kulkarni SB, Lee SC, Park HG, Gurav KV, Kim JH, Jun SC, ACS Appl. Mater. Inter., 6, 2450 (2014)
  42. Wagner CD, Riggs WM, Davis LE, Moulder JF, Muilenberg JE, Handbook of X-ray Photoelectron Spectroscopy, Perkin-Elmer Corporation, U.S.A, 1979.
  43. Plackowski C, Hampton MA, Bruckard WJ, Nguyen AV, Miner. Eng., 55, 60 (2014)
  44. Nguyen VH, Shim JJ, J. Power Sources, 273, 110 (2015)
  45. Kudin KN, Ozbas B, Schniepp HC, Prudhomme RK, Aksay IA, Car R, Nano Lett., 8(1), 36 (2008)
  46. Ferrari AC, Robertson J, Phys. Rev. B, 61(20), 14095 (2000)
  47. Lu Z, Chang Z, Zhu W, Sun X, Chem. Commun., 47, 9651 (2011)
  48. Liu J, Huang X, Li Y, Sulieman KM, Heb X, Sun F, J. Mater. Chem., 16, 4427 (2006)
  49. Tran HD, Arcy JMD, Wang Y, Beltramo PJ, Strong VA, Kaner RB, J. Mater. Chem., 21, 3534 (2011)
  50. Nguyen VH, Charmaine L, Shim JJ, Mater. Lett., 170, 106 (2016)
  51. Nguyen VH, Shim JJ, Mater. Chem. Phys., 176, 6 (2016)
  52. Lamiel C, Nguyen VH, Roh C, Kang C, Shim JJ, Electrochim. Acta, 210, 240 (2016)
  53. Pawar SA, Patil DS, Shin JC, Electrochim. Acta, 259, 664 (2018)
  54. Massey AG, Thompson NR, Johnson BFG, Davis R, The Chemistry of Copper, Silver and Gold, 1st edition, Pergamon Press, 1973.
  55. Faber MS, Dziedzic R, Lukowski MA, Kaiser NS, Ding Q, Jin S, J. Am. Chem. Soc., 136(28), 10053 (2014)
  56. Velasquez P, Leinen D, Pascual J, Ramos-Barrado JR, Grez P, Gomez H, Schrebler R, Del Rio R, Cordova R, J. Phys. Chem. B, 109(11), 4977 (2005)
  57. Zhao YX, Pan HC, Lou YB, Qiu XF, Zhu JJ, Burda C, J. Am. Chem. Soc., 131(12), 4253 (2009)
  58. Qu G, Jia S, Wang H, Cao F, Li L, Qing C, Sun D, Wang B, Tang Y, Wang J, ACS Appl. Mater. Inter., 8, 20822 (2016)
  59. Yan M, Yao Y, Wen J, Long L, Kong M, Zhang G, Liao X, Yin G, Huang Z, ACS Appl. Mater. Inter., 8, 24525 (2016)
  60. Fu W, Han W, Zha H, Mei J, Li Y, Zhang Z, Xie E, Phys. Chem. Chem. Phys., 18, 24471 (2016)
  61. Zhang J, Feng H, Yang J, Qin Q, Fan C, Zheng W, ACS Appl. Mater. Inter., 7(39), 21735 (2015)
  62. Long L, Yao YD, Yan ML, Wang HJ, Zhang GG, Kong ML, Yang L, Liao XM, Yin GF, Huang ZB, J. Mater. Sci., 52(7), 3642 (2017)
  63. Fan H, Niu R, Duan J, Liu W, Shen W, ACS Appl. Mater. Inter., 8, 19475 (2016)
  64. Chen HC, Jiang JJ, Zhang L, Xia DD, Zhao YD, Guo DQ, Qi T, Wan HZ, J. Power Sources, 254, 249 (2014)
  65. Xu XY, Song YH, Xue RN, Zhou JK, Gao JP, Xing FB, Chem. Eng. J., 301, 266 (2016)
  66. Rakhi RB, Alhebshi NA, Anjum DH, Alshareef HN, J. Mater. Chem. A, 2, 16190 (2014)
  67. Lai F, Miao YE, Zuo L, Lu H, Huang Y, Liu T, Small, 12(24), 3235 (2016)