Single-Step Pore-Selective Silver-Functionalized Honeycomb-Patterned Porous Polystyrene Film Using a Modified Breath Figure Metho

Shahkar Falak; Bo Kyoung Shin; Do Sung Huh

Macromolecular Research, Vol.29, No.8, 519-523, August, 2021

DOI10.1007/s13233-021-9070-z Export Citation

Single-Step Pore-Selective Silver-Functionalized Honeycomb-Patterned Porous Polystyrene Film Using a Modified Breath Figure Metho

Shahkar Falak, Bo Kyoung Shin, and Do Sung Huh^†

Department of Chemistry and Nanoscience and Engineering, Centre of Nano Manufacturing, Inje University, Gimhae-si, Gyeongnam 50834, Korea

E-mail:

A fabrication strategy for the pore-selective functionalization of silver (Ag) in the honeycomb-patterned (HCP) porous polystyrene (PS) film was demonstrated by a modified breath figure method accompanying an interfacial chemical reaction. It was performed by casting the polymer solution including ferrocene under humid conditions containing AgNO3. The film showed HCP porous morphology with poreselective Ag coating. The coating of Ag was identified by scanning electron microscopy with energy-dispersive X-ray spectroscopy and elemental mapping analysis. The conductivity of the film was obtained by a four-point probe conductivity measuring method, and it was observed that the conductivity increased by increasing the ferrocene, concentration.

Keywords:Ag-functionalized HCP film;pore-selective coating;breath figure method;interfacial reaction

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[2] Zhang Q, Li M, Luo B, Luo Y, Jiang H, Chen C, Wang S, Min D, J. Hazard. Mater., 402, 123445 (2021)

[3] Lou C, Li Z, Yang C, Liu X, Zheng W, Zhang J, Sens. Actuators B-Chem., 333, 129572 (2021)

[4] Kawano T, Sato M, Yabu H, Shimomura M, Biomater. Sci., 2, 52 (2014)

[5] Du C, Zhang A, Bai H, Li L, ACS Macro Lett., 2, 27 (2013)

[6] An BW, Kim K, Kim M, Kim SY, Hur SH, Park JU, Small, 11, 2263 (2015)

[7] Xie Y, Ye S, Reyes C, Sithikong P, Popa BI, Wiley BJ, Cummer SA, Appl. Phys. Lett., 110, 181903 (2017)

[8] Radke A, Gissibl T, Klotzbucher T, Braun PV, Giessen H, Adv. Mater., 23(27), 3018 (2011)

[9] Widawski G, Rawiso M, Francois B, Nature, 369(6479), 387 (1994)

[10] Rayleigh L, Nature, 86, 416 (1911)

[11] Aitken J, Nature, 90, 619 (1913)

[12] Vohra V, Bolognesi A, Calzaferri G, Botta C, Langmuir, 25(20), 12019 (2009)

[13] Ma H, Cui J, Chen J, Hao J, Chem. Eur. J., 17, 655 (2011)

[14] Vargas-Alfredo N, Santos-Coquillat A, Martinez-Campos E, et al., ACS Appl. Mater. Interfaces, 9, 44270 (2017)

[15] Min E, Wong KH, Stenzel MH, Adv. Mater., 20(18), 3550 (2008)

[16] Boker A, Lin Y, Chiapperini K, Horowitz R, Thompson M, Carreon V, Xu T, Abetz C, Skaff H, Dinsmore AD, Emrick T, Russell TP, Nat. Mater., 3(5), 302 (2004)

[17] Male U, Shin BK, Huh DS, Polymer, 121, 149 (2017)

[18] Cao TT, Male U, Huh DS, Polymer, 153, 86 (2018)

[19] Cao TT, Modigunta JKR, Male U, Huh DS, Adv. Mater. Interfaces, 5, 180174 (2018)

[20] Modigunta JKR, Kim JM, Cao TT, Yabu H, Huh DS, Polymer, 201, 122630 (2020)

[21] Dakal TC, Kumar A, Majumdar RS, Yadav V, Front. Microbiol., 7 (2016).

[22] Jebril S, Jenana RKB, Dridi C, Mater. Chem. Phys., 248, 122898 (2020)

[23] Vukovic JS, Peric-Grujic AA, Mitic-Culafic DS, Nedeljkovic BDB, Tomic SL, Macromol. Res., 28(4), 382 (2020)

[24] Hamouda T, Ibrahim HM, Kafafy HH, Mashaly HM, Mohamed NH, Aly NM, Int. J. Biol. Macromol., 181, 990 (2021)

[25] Reddy PRS, Rao KM, Rao KSVK, Shchipunov Y, Ha CS, Macromol. Res., 22(8), 832 (2014)

[26] Wasef LG, Shaheen HM, El-Sayed YS, Shalaby TI, et al., Biol. Trace Elem. Res., 193, 456 (2020)

[27] Kumarasinghe KGUR, Silva WCH, Fernando MDA, et al., Biomed Res. Int., 2021, 666664 (2021)

[28] Neethu S, Midhun SJ, Radhakrishnan EK, Jyothis M, Microb. Pathog., 138, 103832 (2020)

[29] Noor N, Mutalik S, Younas MW, Chan CY, Thakur S, Wang F, Yao MZ, Mou Q, Leung PHM, Polymers, 11, 2000 (2019)

[30] Salem SS, EL-Belely EF, Niedbała G, Alnoman MM, et al., Nanomaterials, 10, 2082 (2020)

[31] Hanif Z, Khan ZA, Choi D, La M, Park SJ, J. Environ. Chem. Eng., 105535 (2021).

[32] Xu C, Chen W, Gao H, Xie X, Chen Y, Environ. Sci. Nano, 7, 803 (2020)

[33] Laaksonen A, Kovacs H, Can. J. Chem., 72, 2278 (1994)

[34] Iino T, Ohashi K, Inoue K, Judai K, Nishi N, Sekiya H, J. Chem. Phys., 126, 194302 (2007)

[35] Elbert J, Gallei M, Ruttiger C, Brunsen A, Didzoleit H, Stuhn B, Rehahn M, Organometallics, 32, 5873 (2013)

[36] Male U, Shin BK, Huh DS, Polymer, 119, 206 (2017)

[37] Shin BK, Male U, Huh DS, Polymer, 135, 1 (2018)

[38] Kim BS, Basavaraja C, Jo EA, Kim DG, Huh DS, Polymer, 51(15), 3365 (2010)

[39] Luo K, Dryfe RA, New J. Chem., 33, 157 (2009)

[40] Hasse U, Palm GJ, Hinrichs W, Schafer J, Scholz F, Phys. Chem. Chem. Phys., 13, 12254 (2011)